(E)-1-[(2-Fluoro­phen­yl)imino­meth­yl]-2-naphthol–(Z)-1-[(2-fluoro­phen­yl)amino­methyl­idene]naphthalen-2(1H)-one (0.57/0.43)

The title Schiff base compound, 0.57C(17)H(12)FNO·0.43C(17)H(12)FNO, reveals both the enol (OH) and keto (NH) tautomeric forms with occupancies of 0.57 (6) and 0.43 (6), respectively. The tautomeric forms are stabilized by intra­molecular O—H⋯N (enol) and N—H⋯O (keto) hydrogen bonds. The dihedral an...

Descripción completa

Detalles Bibliográficos
Autores principales: Alpaslan, Gökhan, Macit, Mustafa, Büyükgüngör, Orhan, Erdönmez, Ahmet
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979202/
https://www.ncbi.nlm.nih.gov/pubmed/21579219
http://dx.doi.org/10.1107/S1600536810014777
Descripción
Sumario:The title Schiff base compound, 0.57C(17)H(12)FNO·0.43C(17)H(12)FNO, reveals both the enol (OH) and keto (NH) tautomeric forms with occupancies of 0.57 (6) and 0.43 (6), respectively. The tautomeric forms are stabilized by intra­molecular O—H⋯N (enol) and N—H⋯O (keto) hydrogen bonds. The dihedral angle between the naphthalene ring system and the benzene ring is 32.76 (1)°.

Ejemplares similares