(E)-1-[(2-Fluoro­phen­yl)imino­meth­yl]-2-naphthol–(Z)-1-[(2-fluoro­phen­yl)amino­methyl­idene]naphthalen-2(1H)-one (0.57/0.43)

The title Schiff base compound, 0.57C(17)H(12)FNO·0.43C(17)H(12)FNO, reveals both the enol (OH) and keto (NH) tautomeric forms with occupancies of 0.57 (6) and 0.43 (6), respectively. The tautomeric forms are stabilized by intra­molecular O—H⋯N (enol) and N—H⋯O (keto) hydrogen bonds. The dihedral an...

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Detalles Bibliográficos
Autores principales: Alpaslan, Gökhan, Macit, Mustafa, Büyükgüngör, Orhan, Erdönmez, Ahmet
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979202/
https://www.ncbi.nlm.nih.gov/pubmed/21579219
http://dx.doi.org/10.1107/S1600536810014777
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author Alpaslan, Gökhan
Macit, Mustafa
Büyükgüngör, Orhan
Erdönmez, Ahmet
author_facet Alpaslan, Gökhan
Macit, Mustafa
Büyükgüngör, Orhan
Erdönmez, Ahmet
author_sort Alpaslan, Gökhan
collection PubMed
description The title Schiff base compound, 0.57C(17)H(12)FNO·0.43C(17)H(12)FNO, reveals both the enol (OH) and keto (NH) tautomeric forms with occupancies of 0.57 (6) and 0.43 (6), respectively. The tautomeric forms are stabilized by intra­molecular O—H⋯N (enol) and N—H⋯O (keto) hydrogen bonds. The dihedral angle between the naphthalene ring system and the benzene ring is 32.76 (1)°.
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spelling pubmed-29792022010-12-30 (E)-1-[(2-Fluoro­phen­yl)imino­meth­yl]-2-naphthol–(Z)-1-[(2-fluoro­phen­yl)amino­methyl­idene]naphthalen-2(1H)-one (0.57/0.43) Alpaslan, Gökhan Macit, Mustafa Büyükgüngör, Orhan Erdönmez, Ahmet Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, 0.57C(17)H(12)FNO·0.43C(17)H(12)FNO, reveals both the enol (OH) and keto (NH) tautomeric forms with occupancies of 0.57 (6) and 0.43 (6), respectively. The tautomeric forms are stabilized by intra­molecular O—H⋯N (enol) and N—H⋯O (keto) hydrogen bonds. The dihedral angle between the naphthalene ring system and the benzene ring is 32.76 (1)°. International Union of Crystallography 2010-04-28 /pmc/articles/PMC2979202/ /pubmed/21579219 http://dx.doi.org/10.1107/S1600536810014777 Text en © Alpaslan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Alpaslan, Gökhan
Macit, Mustafa
Büyükgüngör, Orhan
Erdönmez, Ahmet
(E)-1-[(2-Fluoro­phen­yl)imino­meth­yl]-2-naphthol–(Z)-1-[(2-fluoro­phen­yl)amino­methyl­idene]naphthalen-2(1H)-one (0.57/0.43)
title (E)-1-[(2-Fluoro­phen­yl)imino­meth­yl]-2-naphthol–(Z)-1-[(2-fluoro­phen­yl)amino­methyl­idene]naphthalen-2(1H)-one (0.57/0.43)
title_full (E)-1-[(2-Fluoro­phen­yl)imino­meth­yl]-2-naphthol–(Z)-1-[(2-fluoro­phen­yl)amino­methyl­idene]naphthalen-2(1H)-one (0.57/0.43)
title_fullStr (E)-1-[(2-Fluoro­phen­yl)imino­meth­yl]-2-naphthol–(Z)-1-[(2-fluoro­phen­yl)amino­methyl­idene]naphthalen-2(1H)-one (0.57/0.43)
title_full_unstemmed (E)-1-[(2-Fluoro­phen­yl)imino­meth­yl]-2-naphthol–(Z)-1-[(2-fluoro­phen­yl)amino­methyl­idene]naphthalen-2(1H)-one (0.57/0.43)
title_short (E)-1-[(2-Fluoro­phen­yl)imino­meth­yl]-2-naphthol–(Z)-1-[(2-fluoro­phen­yl)amino­methyl­idene]naphthalen-2(1H)-one (0.57/0.43)
title_sort (e)-1-[(2-fluoro­phen­yl)imino­meth­yl]-2-naphthol–(z)-1-[(2-fluoro­phen­yl)amino­methyl­idene]naphthalen-2(1h)-one (0.57/0.43)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979202/
https://www.ncbi.nlm.nih.gov/pubmed/21579219
http://dx.doi.org/10.1107/S1600536810014777
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