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{Bis[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}{tris­[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic inter­action

The title compound, [Co(C(10)H(10)BF(6)N(4))(C(15)H(13)BF(9)N(6))], is a neutral Co(II) complex which contains one each of the anionic ligands, bis­(3-trifluoro­methyl-5-methyl­pyrazol-1-yl)borate (Bp) and tris­(3-trifluoro­methyl-5-methyl­pyrazol-1-yl)borate (Tp). A distorted octa­hedral coordinati...

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Detalles Bibliográficos
Autores principales: Stibrany, Robert T., Potenza, Joseph A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979213/
https://www.ncbi.nlm.nih.gov/pubmed/21579005
http://dx.doi.org/10.1107/S1600536810011773
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author Stibrany, Robert T.
Potenza, Joseph A.
author_facet Stibrany, Robert T.
Potenza, Joseph A.
author_sort Stibrany, Robert T.
collection PubMed
description The title compound, [Co(C(10)H(10)BF(6)N(4))(C(15)H(13)BF(9)N(6))], is a neutral Co(II) complex which contains one each of the anionic ligands, bis­(3-trifluoro­methyl-5-methyl­pyrazol-1-yl)borate (Bp) and tris­(3-trifluoro­methyl-5-methyl­pyrazol-1-yl)borate (Tp). A distorted octa­hedral coordination geometry results from ligation of an H atom, which is part of an agostic B—H⋯Co inter­action (H⋯Co = 2.17 Å), and by five imine N atoms, two from a Bp ligand and three from a Tp ligand. In the crystal, mol­ecules form layers parallel to the (10[Image: see text]) planes, and the layers are linked along the a axis by C—H⋯F hydrogen bonds. An intra­molecular C—H⋯F inter­action also occurs.
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spelling pubmed-29792132010-12-30 {Bis[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}{tris­[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic inter­action Stibrany, Robert T. Potenza, Joseph A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(10)H(10)BF(6)N(4))(C(15)H(13)BF(9)N(6))], is a neutral Co(II) complex which contains one each of the anionic ligands, bis­(3-trifluoro­methyl-5-methyl­pyrazol-1-yl)borate (Bp) and tris­(3-trifluoro­methyl-5-methyl­pyrazol-1-yl)borate (Tp). A distorted octa­hedral coordination geometry results from ligation of an H atom, which is part of an agostic B—H⋯Co inter­action (H⋯Co = 2.17 Å), and by five imine N atoms, two from a Bp ligand and three from a Tp ligand. In the crystal, mol­ecules form layers parallel to the (10[Image: see text]) planes, and the layers are linked along the a axis by C—H⋯F hydrogen bonds. An intra­molecular C—H⋯F inter­action also occurs. International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979213/ /pubmed/21579005 http://dx.doi.org/10.1107/S1600536810011773 Text en © Stibrany and Potenza 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Stibrany, Robert T.
Potenza, Joseph A.
{Bis[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}{tris­[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic inter­action
title {Bis[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}{tris­[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic inter­action
title_full {Bis[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}{tris­[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic inter­action
title_fullStr {Bis[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}{tris­[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic inter­action
title_full_unstemmed {Bis[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}{tris­[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic inter­action
title_short {Bis[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}{tris­[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic inter­action
title_sort {bis[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}{tris­[5-methyl-3-(trifluoro­meth­yl)pyrazol-1-yl]borato}cobalt(ii): a structure containing a b—h⋯co agostic inter­action
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979213/
https://www.ncbi.nlm.nih.gov/pubmed/21579005
http://dx.doi.org/10.1107/S1600536810011773
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