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{Bis[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}{tris[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic interaction
The title compound, [Co(C(10)H(10)BF(6)N(4))(C(15)H(13)BF(9)N(6))], is a neutral Co(II) complex which contains one each of the anionic ligands, bis(3-trifluoromethyl-5-methylpyrazol-1-yl)borate (Bp) and tris(3-trifluoromethyl-5-methylpyrazol-1-yl)borate (Tp). A distorted octahedral coordinati...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979213/ https://www.ncbi.nlm.nih.gov/pubmed/21579005 http://dx.doi.org/10.1107/S1600536810011773 |
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author | Stibrany, Robert T. Potenza, Joseph A. |
author_facet | Stibrany, Robert T. Potenza, Joseph A. |
author_sort | Stibrany, Robert T. |
collection | PubMed |
description | The title compound, [Co(C(10)H(10)BF(6)N(4))(C(15)H(13)BF(9)N(6))], is a neutral Co(II) complex which contains one each of the anionic ligands, bis(3-trifluoromethyl-5-methylpyrazol-1-yl)borate (Bp) and tris(3-trifluoromethyl-5-methylpyrazol-1-yl)borate (Tp). A distorted octahedral coordination geometry results from ligation of an H atom, which is part of an agostic B—H⋯Co interaction (H⋯Co = 2.17 Å), and by five imine N atoms, two from a Bp ligand and three from a Tp ligand. In the crystal, molecules form layers parallel to the (10[Image: see text]) planes, and the layers are linked along the a axis by C—H⋯F hydrogen bonds. An intramolecular C—H⋯F interaction also occurs. |
format | Text |
id | pubmed-2979213 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29792132010-12-30 {Bis[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}{tris[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic interaction Stibrany, Robert T. Potenza, Joseph A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(10)H(10)BF(6)N(4))(C(15)H(13)BF(9)N(6))], is a neutral Co(II) complex which contains one each of the anionic ligands, bis(3-trifluoromethyl-5-methylpyrazol-1-yl)borate (Bp) and tris(3-trifluoromethyl-5-methylpyrazol-1-yl)borate (Tp). A distorted octahedral coordination geometry results from ligation of an H atom, which is part of an agostic B—H⋯Co interaction (H⋯Co = 2.17 Å), and by five imine N atoms, two from a Bp ligand and three from a Tp ligand. In the crystal, molecules form layers parallel to the (10[Image: see text]) planes, and the layers are linked along the a axis by C—H⋯F hydrogen bonds. An intramolecular C—H⋯F interaction also occurs. International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979213/ /pubmed/21579005 http://dx.doi.org/10.1107/S1600536810011773 Text en © Stibrany and Potenza 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Stibrany, Robert T. Potenza, Joseph A. {Bis[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}{tris[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic interaction |
title | {Bis[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}{tris[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic interaction |
title_full | {Bis[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}{tris[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic interaction |
title_fullStr | {Bis[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}{tris[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic interaction |
title_full_unstemmed | {Bis[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}{tris[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic interaction |
title_short | {Bis[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}{tris[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}cobalt(II): a structure containing a B—H⋯Co agostic interaction |
title_sort | {bis[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}{tris[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]borato}cobalt(ii): a structure containing a b—h⋯co agostic interaction |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979213/ https://www.ncbi.nlm.nih.gov/pubmed/21579005 http://dx.doi.org/10.1107/S1600536810011773 |
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