Diphen­yl[2-(2-pyridylamino­meth­yl)phen­yl]phosphine oxide

The title compound, C(24)H(21)N(2)OP, was obtained by reacting 2-amino­pyridine and 2-(diphenyl­phosphin­yl)benzaldehyde in ethanol. It crystallizes with two crystallographically independent mol­ecules in the asymmetric unit. The amino­pyridine units and the benzene ring bonded to the phosphine oxid...

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Detalles Bibliográficos
Autores principales: Hernández-Ortega, Simón, Cuenu Cabeza, Fernando, Cabrera-Ortiz, Armando
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979214/
https://www.ncbi.nlm.nih.gov/pubmed/21579222
http://dx.doi.org/10.1107/S1600536810014893
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author Hernández-Ortega, Simón
Cuenu Cabeza, Fernando
Cabrera-Ortiz, Armando
author_facet Hernández-Ortega, Simón
Cuenu Cabeza, Fernando
Cabrera-Ortiz, Armando
author_sort Hernández-Ortega, Simón
collection PubMed
description The title compound, C(24)H(21)N(2)OP, was obtained by reacting 2-amino­pyridine and 2-(diphenyl­phosphin­yl)benzaldehyde in ethanol. It crystallizes with two crystallographically independent mol­ecules in the asymmetric unit. The amino­pyridine units and the benzene ring bonded to the phosphine oxide P atom form dihedral angles of 88.58 (7) and 82.47 (9)° in the two mol­ecules. The crystal structure displays strong N—H⋯O and weak C—H⋯O hydrogen bonds along the b axis and C—H⋯π aromatic intra- and inter­molecular inter­actions.
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spelling pubmed-29792142010-12-30 Diphen­yl[2-(2-pyridylamino­meth­yl)phen­yl]phosphine oxide Hernández-Ortega, Simón Cuenu Cabeza, Fernando Cabrera-Ortiz, Armando Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(21)N(2)OP, was obtained by reacting 2-amino­pyridine and 2-(diphenyl­phosphin­yl)benzaldehyde in ethanol. It crystallizes with two crystallographically independent mol­ecules in the asymmetric unit. The amino­pyridine units and the benzene ring bonded to the phosphine oxide P atom form dihedral angles of 88.58 (7) and 82.47 (9)° in the two mol­ecules. The crystal structure displays strong N—H⋯O and weak C—H⋯O hydrogen bonds along the b axis and C—H⋯π aromatic intra- and inter­molecular inter­actions. International Union of Crystallography 2010-04-28 /pmc/articles/PMC2979214/ /pubmed/21579222 http://dx.doi.org/10.1107/S1600536810014893 Text en © Hernández-Ortega et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hernández-Ortega, Simón
Cuenu Cabeza, Fernando
Cabrera-Ortiz, Armando
Diphen­yl[2-(2-pyridylamino­meth­yl)phen­yl]phosphine oxide
title Diphen­yl[2-(2-pyridylamino­meth­yl)phen­yl]phosphine oxide
title_full Diphen­yl[2-(2-pyridylamino­meth­yl)phen­yl]phosphine oxide
title_fullStr Diphen­yl[2-(2-pyridylamino­meth­yl)phen­yl]phosphine oxide
title_full_unstemmed Diphen­yl[2-(2-pyridylamino­meth­yl)phen­yl]phosphine oxide
title_short Diphen­yl[2-(2-pyridylamino­meth­yl)phen­yl]phosphine oxide
title_sort diphen­yl[2-(2-pyridylamino­meth­yl)phen­yl]phosphine oxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979214/
https://www.ncbi.nlm.nih.gov/pubmed/21579222
http://dx.doi.org/10.1107/S1600536810014893
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AT cuenucabezafernando diphenyl22pyridylaminomethylphenylphosphineoxide
AT cabreraortizarmando diphenyl22pyridylaminomethylphenylphosphineoxide

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