Dilead(II) chromium(III) hepta­fluoride

Single crystals of the title compound, Pb(2)CrF(7), were obtained by solid-state reaction. The monoclinic structure is isotypic with Pb(2)RhF(7) and is built up of CrF(6) (3−) octa­hedra isolated from each other, inserted in a fluorite-related matrix of PbF(6) distorted octa­hedra, and PbF(8) square...

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Detalles Bibliográficos
Autor principal: Le Bail, Armel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979219/
https://www.ncbi.nlm.nih.gov/pubmed/21578982
http://dx.doi.org/10.1107/S1600536810011608
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author Le Bail, Armel
author_facet Le Bail, Armel
author_sort Le Bail, Armel
collection PubMed
description Single crystals of the title compound, Pb(2)CrF(7), were obtained by solid-state reaction. The monoclinic structure is isotypic with Pb(2)RhF(7) and is built up of CrF(6) (3−) octa­hedra isolated from each other, inserted in a fluorite-related matrix of PbF(6) distorted octa­hedra, and PbF(8) square anti­prisms sharing edges and corners. The seventh F atom is ‘independent’, connected only to three Pb atoms within FPb(3) triangles, sharing an edge and building an almost planar Pb(4)F(2) unit, so that the formula can alternatively be written as Pb(2)F(CrF(6)).
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spelling pubmed-29792192010-12-30 Dilead(II) chromium(III) hepta­fluoride Le Bail, Armel Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of the title compound, Pb(2)CrF(7), were obtained by solid-state reaction. The monoclinic structure is isotypic with Pb(2)RhF(7) and is built up of CrF(6) (3−) octa­hedra isolated from each other, inserted in a fluorite-related matrix of PbF(6) distorted octa­hedra, and PbF(8) square anti­prisms sharing edges and corners. The seventh F atom is ‘independent’, connected only to three Pb atoms within FPb(3) triangles, sharing an edge and building an almost planar Pb(4)F(2) unit, so that the formula can alternatively be written as Pb(2)F(CrF(6)). International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979219/ /pubmed/21578982 http://dx.doi.org/10.1107/S1600536810011608 Text en © Armel Le Bail 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Le Bail, Armel
Dilead(II) chromium(III) hepta­fluoride
title Dilead(II) chromium(III) hepta­fluoride
title_full Dilead(II) chromium(III) hepta­fluoride
title_fullStr Dilead(II) chromium(III) hepta­fluoride
title_full_unstemmed Dilead(II) chromium(III) hepta­fluoride
title_short Dilead(II) chromium(III) hepta­fluoride
title_sort dilead(ii) chromium(iii) hepta­fluoride
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979219/
https://www.ncbi.nlm.nih.gov/pubmed/21578982
http://dx.doi.org/10.1107/S1600536810011608
work_keys_str_mv AT lebailarmel dileadiichromiumiiiheptafluoride

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