{N-[(2-Oxido-1-naphth­yl)methyl­idene]­serinato-κ(3) O,N,O′}(1,10-phenanthroline-κ(2) N,N′)copper(II)

In the title complex, [Cu(C(14)H(11)NO(4))(C(12)H(8)N(2))], the tridentate Schiff base ligand is derived from the condensation of 2-hydr­oxy-1-naphthaldehyde and l-serine. The Cu(II) atom is five-coordinated by one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 1,10-phe...

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Detalles Bibliográficos
Autores principales: Li, Jinghong, Guo, Zhenghua, Li, Lianzhi, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979222/
https://www.ncbi.nlm.nih.gov/pubmed/21579013
http://dx.doi.org/10.1107/S1600536810012675
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author Li, Jinghong
Guo, Zhenghua
Li, Lianzhi
Wang, Daqi
author_facet Li, Jinghong
Guo, Zhenghua
Li, Lianzhi
Wang, Daqi
author_sort Li, Jinghong
collection PubMed
description In the title complex, [Cu(C(14)H(11)NO(4))(C(12)H(8)N(2))], the tridentate Schiff base ligand is derived from the condensation of 2-hydr­oxy-1-naphthaldehyde and l-serine. The Cu(II) atom is five-coordinated by one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. In the crystal structure, the combination of inter­molecular O—H⋯O and C—H⋯O hydrogen bonds results in a two-dimensional network structure parallel to (001).
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spelling pubmed-29792222010-12-30 {N-[(2-Oxido-1-naphth­yl)methyl­idene]­serinato-κ(3) O,N,O′}(1,10-phenanthroline-κ(2) N,N′)copper(II) Li, Jinghong Guo, Zhenghua Li, Lianzhi Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(14)H(11)NO(4))(C(12)H(8)N(2))], the tridentate Schiff base ligand is derived from the condensation of 2-hydr­oxy-1-naphthaldehyde and l-serine. The Cu(II) atom is five-coordinated by one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. In the crystal structure, the combination of inter­molecular O—H⋯O and C—H⋯O hydrogen bonds results in a two-dimensional network structure parallel to (001). International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979222/ /pubmed/21579013 http://dx.doi.org/10.1107/S1600536810012675 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Jinghong
Guo, Zhenghua
Li, Lianzhi
Wang, Daqi
{N-[(2-Oxido-1-naphth­yl)methyl­idene]­serinato-κ(3) O,N,O′}(1,10-phenanthroline-κ(2) N,N′)copper(II)
title {N-[(2-Oxido-1-naphth­yl)methyl­idene]­serinato-κ(3) O,N,O′}(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full {N-[(2-Oxido-1-naphth­yl)methyl­idene]­serinato-κ(3) O,N,O′}(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_fullStr {N-[(2-Oxido-1-naphth­yl)methyl­idene]­serinato-κ(3) O,N,O′}(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full_unstemmed {N-[(2-Oxido-1-naphth­yl)methyl­idene]­serinato-κ(3) O,N,O′}(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_short {N-[(2-Oxido-1-naphth­yl)methyl­idene]­serinato-κ(3) O,N,O′}(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_sort {n-[(2-oxido-1-naphth­yl)methyl­idene]­serinato-κ(3) o,n,o′}(1,10-phenanthroline-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979222/
https://www.ncbi.nlm.nih.gov/pubmed/21579013
http://dx.doi.org/10.1107/S1600536810012675
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AT lilianzhi n2oxido1naphthylmethylideneserinatok3ono110phenanthrolinek2nncopperii
AT wangdaqi n2oxido1naphthylmethylideneserinatok3ono110phenanthrolinek2nncopperii

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