{1,3-Bis[(diphenyl­phosphanyl-κP)­oxy]prop-2-yl-κC (2)}iodido(trimethyl­phosphane)cobalt(II)

The title compound, [Co(C(27)H(25)O(2)P(2))I(C(3)H(9)P)], was synthesized by the addition of 1-iodo­butane to a solution of the parent cobalt complex {1,3-bis­[(diphenyl­phosphan­yl)­oxy]prop-2-yl}bis­(trimethyl­phosphane)cobalt(II). Two five-membered cobaltocycles with considerable ring bending (su...

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Detalles Bibliográficos
Autores principales: Xu, Guoqiang, Li, Xiaoyan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979230/
https://www.ncbi.nlm.nih.gov/pubmed/21579033
http://dx.doi.org/10.1107/S1600536810013747
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author Xu, Guoqiang
Li, Xiaoyan
author_facet Xu, Guoqiang
Li, Xiaoyan
author_sort Xu, Guoqiang
collection PubMed
description The title compound, [Co(C(27)H(25)O(2)P(2))I(C(3)H(9)P)], was synthesized by the addition of 1-iodo­butane to a solution of the parent cobalt complex {1,3-bis­[(diphenyl­phosphan­yl)­oxy]prop-2-yl}bis­(trimethyl­phosphane)cobalt(II). Two five-membered cobaltocycles with considerable ring bending (sum of inter­nal angles = 516.4 and 517.7°) are formed through two P atoms of the PPh(2) groups and a metallated Csp (3) atom. The Co(II) atom is centered in a trigonal-bipyramidal configuration.
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spelling pubmed-29792302010-12-30 {1,3-Bis[(diphenyl­phosphanyl-κP)­oxy]prop-2-yl-κC (2)}iodido(trimethyl­phosphane)cobalt(II) Xu, Guoqiang Li, Xiaoyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(27)H(25)O(2)P(2))I(C(3)H(9)P)], was synthesized by the addition of 1-iodo­butane to a solution of the parent cobalt complex {1,3-bis­[(diphenyl­phosphan­yl)­oxy]prop-2-yl}bis­(trimethyl­phosphane)cobalt(II). Two five-membered cobaltocycles with considerable ring bending (sum of inter­nal angles = 516.4 and 517.7°) are formed through two P atoms of the PPh(2) groups and a metallated Csp (3) atom. The Co(II) atom is centered in a trigonal-bipyramidal configuration. International Union of Crystallography 2010-04-21 /pmc/articles/PMC2979230/ /pubmed/21579033 http://dx.doi.org/10.1107/S1600536810013747 Text en © Xu and Li 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Guoqiang
Li, Xiaoyan
{1,3-Bis[(diphenyl­phosphanyl-κP)­oxy]prop-2-yl-κC (2)}iodido(trimethyl­phosphane)cobalt(II)
title {1,3-Bis[(diphenyl­phosphanyl-κP)­oxy]prop-2-yl-κC (2)}iodido(trimethyl­phosphane)cobalt(II)
title_full {1,3-Bis[(diphenyl­phosphanyl-κP)­oxy]prop-2-yl-κC (2)}iodido(trimethyl­phosphane)cobalt(II)
title_fullStr {1,3-Bis[(diphenyl­phosphanyl-κP)­oxy]prop-2-yl-κC (2)}iodido(trimethyl­phosphane)cobalt(II)
title_full_unstemmed {1,3-Bis[(diphenyl­phosphanyl-κP)­oxy]prop-2-yl-κC (2)}iodido(trimethyl­phosphane)cobalt(II)
title_short {1,3-Bis[(diphenyl­phosphanyl-κP)­oxy]prop-2-yl-κC (2)}iodido(trimethyl­phosphane)cobalt(II)
title_sort {1,3-bis[(diphenyl­phosphanyl-κp)­oxy]prop-2-yl-κc (2)}iodido(trimethyl­phosphane)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979230/
https://www.ncbi.nlm.nih.gov/pubmed/21579033
http://dx.doi.org/10.1107/S1600536810013747
work_keys_str_mv AT xuguoqiang 13bisdiphenylphosphanylkpoxyprop2ylkc2iodidotrimethylphosphanecobaltii
AT lixiaoyan 13bisdiphenylphosphanylkpoxyprop2ylkc2iodidotrimethylphosphanecobaltii

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