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(Dimethylformamide-κO)[2-methoxy-6-(2-pyridylmethyliminomethyl)phenolato-κ(3) N,N′,O (1)](thiocyanato-κN)copper(II)
In the title compound, [Cu(C(14)H(13)N(2)O(2))(NCS)(C(3)H(7)NO)], the Cu(2+) ion is coordinated by an N,N′,O-tridentate 2-methoxy-6-(2-pyridylmethyliminomethyl)phenolate ligand, an N-bonded thiocyanate ion and an O-bonded dimethylformamide (DMF) molecule, resulting in a distorted CuN(3)O(2) s...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979238/ https://www.ncbi.nlm.nih.gov/pubmed/21579045 http://dx.doi.org/10.1107/S1600536810014212 |
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author | Bao, Qianqian Chen, Xiaodan Rong, Rong Shi, Feifei |
author_facet | Bao, Qianqian Chen, Xiaodan Rong, Rong Shi, Feifei |
author_sort | Bao, Qianqian |
collection | PubMed |
description | In the title compound, [Cu(C(14)H(13)N(2)O(2))(NCS)(C(3)H(7)NO)], the Cu(2+) ion is coordinated by an N,N′,O-tridentate 2-methoxy-6-(2-pyridylmethyliminomethyl)phenolate ligand, an N-bonded thiocyanate ion and an O-bonded dimethylformamide (DMF) molecule, resulting in a distorted CuN(3)O(2) square-based pyramidal geometry for the metal ion, with the DMF O atom in the apical site. The dihedral angle between the aromatic rings in the ligand is 8.70 (16)°. The S atom is disordered over two positions in a 0.901 (6):0.099 (6) ratio. In the crystal, molecules interact by way of π–π stacking interactions [centroid–centroid separation = 3.720 (2) Å]. |
format | Text |
id | pubmed-2979238 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29792382010-12-30 (Dimethylformamide-κO)[2-methoxy-6-(2-pyridylmethyliminomethyl)phenolato-κ(3) N,N′,O (1)](thiocyanato-κN)copper(II) Bao, Qianqian Chen, Xiaodan Rong, Rong Shi, Feifei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(14)H(13)N(2)O(2))(NCS)(C(3)H(7)NO)], the Cu(2+) ion is coordinated by an N,N′,O-tridentate 2-methoxy-6-(2-pyridylmethyliminomethyl)phenolate ligand, an N-bonded thiocyanate ion and an O-bonded dimethylformamide (DMF) molecule, resulting in a distorted CuN(3)O(2) square-based pyramidal geometry for the metal ion, with the DMF O atom in the apical site. The dihedral angle between the aromatic rings in the ligand is 8.70 (16)°. The S atom is disordered over two positions in a 0.901 (6):0.099 (6) ratio. In the crystal, molecules interact by way of π–π stacking interactions [centroid–centroid separation = 3.720 (2) Å]. International Union of Crystallography 2010-04-24 /pmc/articles/PMC2979238/ /pubmed/21579045 http://dx.doi.org/10.1107/S1600536810014212 Text en © Bao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bao, Qianqian Chen, Xiaodan Rong, Rong Shi, Feifei (Dimethylformamide-κO)[2-methoxy-6-(2-pyridylmethyliminomethyl)phenolato-κ(3) N,N′,O (1)](thiocyanato-κN)copper(II) |
title | (Dimethylformamide-κO)[2-methoxy-6-(2-pyridylmethyliminomethyl)phenolato-κ(3)
N,N′,O
(1)](thiocyanato-κN)copper(II) |
title_full | (Dimethylformamide-κO)[2-methoxy-6-(2-pyridylmethyliminomethyl)phenolato-κ(3)
N,N′,O
(1)](thiocyanato-κN)copper(II) |
title_fullStr | (Dimethylformamide-κO)[2-methoxy-6-(2-pyridylmethyliminomethyl)phenolato-κ(3)
N,N′,O
(1)](thiocyanato-κN)copper(II) |
title_full_unstemmed | (Dimethylformamide-κO)[2-methoxy-6-(2-pyridylmethyliminomethyl)phenolato-κ(3)
N,N′,O
(1)](thiocyanato-κN)copper(II) |
title_short | (Dimethylformamide-κO)[2-methoxy-6-(2-pyridylmethyliminomethyl)phenolato-κ(3)
N,N′,O
(1)](thiocyanato-κN)copper(II) |
title_sort | (dimethylformamide-κo)[2-methoxy-6-(2-pyridylmethyliminomethyl)phenolato-κ(3)
n,n′,o
(1)](thiocyanato-κn)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979238/ https://www.ncbi.nlm.nih.gov/pubmed/21579045 http://dx.doi.org/10.1107/S1600536810014212 |
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