Diytterbium(II) lithium indium(III) digermanide, Yb(2)LiInGe(2)

The title compound, Yb(2)LiInGe(2), a new ordered quaternary inter­metallic phase, crystallizes with the ortho­rhom­bic Ca(2)LiInGe(2) type (Pearson code oP24). The crystal structure contains six crystallographically unique sites in the asymmetric unit, all in special positions with site symmetry .m...

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Detalles Bibliográficos
Autores principales: You, Tae-Soo, Bobev, Svilen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979241/
https://www.ncbi.nlm.nih.gov/pubmed/21578989
http://dx.doi.org/10.1107/S1600536810014595
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author You, Tae-Soo
Bobev, Svilen
author_facet You, Tae-Soo
Bobev, Svilen
author_sort You, Tae-Soo
collection PubMed
description The title compound, Yb(2)LiInGe(2), a new ordered quaternary inter­metallic phase, crystallizes with the ortho­rhom­bic Ca(2)LiInGe(2) type (Pearson code oP24). The crystal structure contains six crystallographically unique sites in the asymmetric unit, all in special positions with site symmetry .m.. The structure is complex and based on [InGe(4)] tetra­hedra, which share corners in two directions, forming layers parallel to (001). Yb atoms fill square-pyramidal (Yb1) and octa­hedral (Yb2) inter­stices between the [InGe(4/2)] layers, while the small Li(+) atoms fill tetra­hedral sites.
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spelling pubmed-29792412010-12-30 Diytterbium(II) lithium indium(III) digermanide, Yb(2)LiInGe(2) You, Tae-Soo Bobev, Svilen Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, Yb(2)LiInGe(2), a new ordered quaternary inter­metallic phase, crystallizes with the ortho­rhom­bic Ca(2)LiInGe(2) type (Pearson code oP24). The crystal structure contains six crystallographically unique sites in the asymmetric unit, all in special positions with site symmetry .m.. The structure is complex and based on [InGe(4)] tetra­hedra, which share corners in two directions, forming layers parallel to (001). Yb atoms fill square-pyramidal (Yb1) and octa­hedral (Yb2) inter­stices between the [InGe(4/2)] layers, while the small Li(+) atoms fill tetra­hedral sites. International Union of Crystallography 2010-04-28 /pmc/articles/PMC2979241/ /pubmed/21578989 http://dx.doi.org/10.1107/S1600536810014595 Text en © You and Bobev 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
You, Tae-Soo
Bobev, Svilen
Diytterbium(II) lithium indium(III) digermanide, Yb(2)LiInGe(2)
title Diytterbium(II) lithium indium(III) digermanide, Yb(2)LiInGe(2)
title_full Diytterbium(II) lithium indium(III) digermanide, Yb(2)LiInGe(2)
title_fullStr Diytterbium(II) lithium indium(III) digermanide, Yb(2)LiInGe(2)
title_full_unstemmed Diytterbium(II) lithium indium(III) digermanide, Yb(2)LiInGe(2)
title_short Diytterbium(II) lithium indium(III) digermanide, Yb(2)LiInGe(2)
title_sort diytterbium(ii) lithium indium(iii) digermanide, yb(2)liinge(2)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979241/
https://www.ncbi.nlm.nih.gov/pubmed/21578989
http://dx.doi.org/10.1107/S1600536810014595
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