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μ-Acetato-bis­(μ-2-{[(3-chloro-2-hydroxy­prop­yl)(2-pyridylmeth­yl)amino]meth­yl}phenolato)dinickel(II) chloride

The title salt, [Ni(2)(C(16)H(18)ClN(2)O(2))(2)(CH(3)COO)]Cl, features a dinuclear cation in which the Ni atoms are triply bridged by two phenolate O ligands and a bidentate acetate ligand with all of the bridging distances essentially symmetric. Each Ni atom is also coordinated by the amine N, pyri...

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Detalles Bibliográficos
Autores principales: Tiekink, Edward R. T., Wardell, James L., Fernandes, Christiane, Horn, Adolfo, Skakle, Janet M. S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979245/
https://www.ncbi.nlm.nih.gov/pubmed/21579048
http://dx.doi.org/10.1107/S160053681001442X
Descripción
Sumario:The title salt, [Ni(2)(C(16)H(18)ClN(2)O(2))(2)(CH(3)COO)]Cl, features a dinuclear cation in which the Ni atoms are triply bridged by two phenolate O ligands and a bidentate acetate ligand with all of the bridging distances essentially symmetric. Each Ni atom is also coordinated by the amine N, pyridine N and hydr­oxy O atoms of the 2-{[(3-chloro-2-hydroxy­prop­yl)(2-pyridylmeth­yl)amino]meth­yl}phenolate ligand which is, therefore, penta­dentate. The resultant N(3)O(3) donor sets define octa­hedral coordination geometries. The chloride counter-anion is connected to the cation via two O(hydr­oxy)—H⋯Cl hydrogen bonds.