μ-Acetato-bis­(μ-2-{[(3-chloro-2-hydroxy­prop­yl)(2-pyridylmeth­yl)amino]meth­yl}phenolato)dinickel(II) chloride

The title salt, [Ni(2)(C(16)H(18)ClN(2)O(2))(2)(CH(3)COO)]Cl, features a dinuclear cation in which the Ni atoms are triply bridged by two phenolate O ligands and a bidentate acetate ligand with all of the bridging distances essentially symmetric. Each Ni atom is also coordinated by the amine N, pyri...

Descripción completa

Detalles Bibliográficos
Autores principales: Tiekink, Edward R. T., Wardell, James L., Fernandes, Christiane, Horn, Adolfo, Skakle, Janet M. S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979245/
https://www.ncbi.nlm.nih.gov/pubmed/21579048
http://dx.doi.org/10.1107/S160053681001442X
_version_ 1782191377956732928
author Tiekink, Edward R. T.
Wardell, James L.
Fernandes, Christiane
Horn, Adolfo
Skakle, Janet M. S.
author_facet Tiekink, Edward R. T.
Wardell, James L.
Fernandes, Christiane
Horn, Adolfo
Skakle, Janet M. S.
author_sort Tiekink, Edward R. T.
collection PubMed
description The title salt, [Ni(2)(C(16)H(18)ClN(2)O(2))(2)(CH(3)COO)]Cl, features a dinuclear cation in which the Ni atoms are triply bridged by two phenolate O ligands and a bidentate acetate ligand with all of the bridging distances essentially symmetric. Each Ni atom is also coordinated by the amine N, pyridine N and hydr­oxy O atoms of the 2-{[(3-chloro-2-hydroxy­prop­yl)(2-pyridylmeth­yl)amino]meth­yl}phenolate ligand which is, therefore, penta­dentate. The resultant N(3)O(3) donor sets define octa­hedral coordination geometries. The chloride counter-anion is connected to the cation via two O(hydr­oxy)—H⋯Cl hydrogen bonds.
format Text
id pubmed-2979245
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29792452010-12-30 μ-Acetato-bis­(μ-2-{[(3-chloro-2-hydroxy­prop­yl)(2-pyridylmeth­yl)amino]meth­yl}phenolato)dinickel(II) chloride Tiekink, Edward R. T. Wardell, James L. Fernandes, Christiane Horn, Adolfo Skakle, Janet M. S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title salt, [Ni(2)(C(16)H(18)ClN(2)O(2))(2)(CH(3)COO)]Cl, features a dinuclear cation in which the Ni atoms are triply bridged by two phenolate O ligands and a bidentate acetate ligand with all of the bridging distances essentially symmetric. Each Ni atom is also coordinated by the amine N, pyridine N and hydr­oxy O atoms of the 2-{[(3-chloro-2-hydroxy­prop­yl)(2-pyridylmeth­yl)amino]meth­yl}phenolate ligand which is, therefore, penta­dentate. The resultant N(3)O(3) donor sets define octa­hedral coordination geometries. The chloride counter-anion is connected to the cation via two O(hydr­oxy)—H⋯Cl hydrogen bonds. International Union of Crystallography 2010-04-24 /pmc/articles/PMC2979245/ /pubmed/21579048 http://dx.doi.org/10.1107/S160053681001442X Text en © Tiekink et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tiekink, Edward R. T.
Wardell, James L.
Fernandes, Christiane
Horn, Adolfo
Skakle, Janet M. S.
μ-Acetato-bis­(μ-2-{[(3-chloro-2-hydroxy­prop­yl)(2-pyridylmeth­yl)amino]meth­yl}phenolato)dinickel(II) chloride
title μ-Acetato-bis­(μ-2-{[(3-chloro-2-hydroxy­prop­yl)(2-pyridylmeth­yl)amino]meth­yl}phenolato)dinickel(II) chloride
title_full μ-Acetato-bis­(μ-2-{[(3-chloro-2-hydroxy­prop­yl)(2-pyridylmeth­yl)amino]meth­yl}phenolato)dinickel(II) chloride
title_fullStr μ-Acetato-bis­(μ-2-{[(3-chloro-2-hydroxy­prop­yl)(2-pyridylmeth­yl)amino]meth­yl}phenolato)dinickel(II) chloride
title_full_unstemmed μ-Acetato-bis­(μ-2-{[(3-chloro-2-hydroxy­prop­yl)(2-pyridylmeth­yl)amino]meth­yl}phenolato)dinickel(II) chloride
title_short μ-Acetato-bis­(μ-2-{[(3-chloro-2-hydroxy­prop­yl)(2-pyridylmeth­yl)amino]meth­yl}phenolato)dinickel(II) chloride
title_sort μ-acetato-bis­(μ-2-{[(3-chloro-2-hydroxy­prop­yl)(2-pyridylmeth­yl)amino]meth­yl}phenolato)dinickel(ii) chloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979245/
https://www.ncbi.nlm.nih.gov/pubmed/21579048
http://dx.doi.org/10.1107/S160053681001442X
work_keys_str_mv AT tiekinkedwardrt macetatobism23chloro2hydroxypropyl2pyridylmethylaminomethylphenolatodinickeliichloride
AT wardelljamesl macetatobism23chloro2hydroxypropyl2pyridylmethylaminomethylphenolatodinickeliichloride
AT fernandeschristiane macetatobism23chloro2hydroxypropyl2pyridylmethylaminomethylphenolatodinickeliichloride
AT hornadolfo macetatobism23chloro2hydroxypropyl2pyridylmethylaminomethylphenolatodinickeliichloride
AT skaklejanetms macetatobism23chloro2hydroxypropyl2pyridylmethylaminomethylphenolatodinickeliichloride

Ejemplares similares