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Poly[dimethano­lbis[μ-5-(3-pyrid­yl)tetra­zolato-κ(2) N (2):N (5)]copper(II)]

In the crystal structure of the title complex, [Cu(C(6)H(4)N(5))(2)(CH(3)OH)(2)](n), the Cu(II) cation lies on an inversion center and is coordinated by four 5-(3-pyrid­yl)tetra­zolate anions and two methanol mol­ecules in an elongated distorted CuN(4)O(2) octa­hedral geometry. Each 5-(3-pyrid­yl)te...

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Detalles Bibliográficos
Autor principal: Wei, Xiao-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979253/
https://www.ncbi.nlm.nih.gov/pubmed/21579037
http://dx.doi.org/10.1107/S1600536810013553
Descripción
Sumario:In the crystal structure of the title complex, [Cu(C(6)H(4)N(5))(2)(CH(3)OH)(2)](n), the Cu(II) cation lies on an inversion center and is coordinated by four 5-(3-pyrid­yl)tetra­zolate anions and two methanol mol­ecules in an elongated distorted CuN(4)O(2) octa­hedral geometry. Each 5-(3-pyrid­yl)tetra­zolate anion bridges two Cu(II) cations, forming a two-dimensional polymeric complex with (4,4) network topology. In the crystal structure, the two-dimensional layers are connected by inter­molecular O—H⋯N hydrogen bonding, forming a three-dimensional supra­molecular architecture.