Poly[dimethano­lbis[μ-5-(3-pyrid­yl)tetra­zolato-κ(2) N (2):N (5)]copper(II)]

In the crystal structure of the title complex, [Cu(C(6)H(4)N(5))(2)(CH(3)OH)(2)](n), the Cu(II) cation lies on an inversion center and is coordinated by four 5-(3-pyrid­yl)tetra­zolate anions and two methanol mol­ecules in an elongated distorted CuN(4)O(2) octa­hedral geometry. Each 5-(3-pyrid­yl)te...

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Autor principal: Wei, Xiao-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979253/
https://www.ncbi.nlm.nih.gov/pubmed/21579037
http://dx.doi.org/10.1107/S1600536810013553
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author Wei, Xiao-Hong
author_facet Wei, Xiao-Hong
author_sort Wei, Xiao-Hong
collection PubMed
description In the crystal structure of the title complex, [Cu(C(6)H(4)N(5))(2)(CH(3)OH)(2)](n), the Cu(II) cation lies on an inversion center and is coordinated by four 5-(3-pyrid­yl)tetra­zolate anions and two methanol mol­ecules in an elongated distorted CuN(4)O(2) octa­hedral geometry. Each 5-(3-pyrid­yl)tetra­zolate anion bridges two Cu(II) cations, forming a two-dimensional polymeric complex with (4,4) network topology. In the crystal structure, the two-dimensional layers are connected by inter­molecular O—H⋯N hydrogen bonding, forming a three-dimensional supra­molecular architecture.
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spelling pubmed-29792532010-12-30 Poly[dimethano­lbis[μ-5-(3-pyrid­yl)tetra­zolato-κ(2) N (2):N (5)]copper(II)] Wei, Xiao-Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, [Cu(C(6)H(4)N(5))(2)(CH(3)OH)(2)](n), the Cu(II) cation lies on an inversion center and is coordinated by four 5-(3-pyrid­yl)tetra­zolate anions and two methanol mol­ecules in an elongated distorted CuN(4)O(2) octa­hedral geometry. Each 5-(3-pyrid­yl)tetra­zolate anion bridges two Cu(II) cations, forming a two-dimensional polymeric complex with (4,4) network topology. In the crystal structure, the two-dimensional layers are connected by inter­molecular O—H⋯N hydrogen bonding, forming a three-dimensional supra­molecular architecture. International Union of Crystallography 2010-04-21 /pmc/articles/PMC2979253/ /pubmed/21579037 http://dx.doi.org/10.1107/S1600536810013553 Text en © Xiao-Hong Wei 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wei, Xiao-Hong
Poly[dimethano­lbis[μ-5-(3-pyrid­yl)tetra­zolato-κ(2) N (2):N (5)]copper(II)]
title Poly[dimethano­lbis[μ-5-(3-pyrid­yl)tetra­zolato-κ(2) N (2):N (5)]copper(II)]
title_full Poly[dimethano­lbis[μ-5-(3-pyrid­yl)tetra­zolato-κ(2) N (2):N (5)]copper(II)]
title_fullStr Poly[dimethano­lbis[μ-5-(3-pyrid­yl)tetra­zolato-κ(2) N (2):N (5)]copper(II)]
title_full_unstemmed Poly[dimethano­lbis[μ-5-(3-pyrid­yl)tetra­zolato-κ(2) N (2):N (5)]copper(II)]
title_short Poly[dimethano­lbis[μ-5-(3-pyrid­yl)tetra­zolato-κ(2) N (2):N (5)]copper(II)]
title_sort poly[dimethano­lbis[μ-5-(3-pyrid­yl)tetra­zolato-κ(2) n (2):n (5)]copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979253/
https://www.ncbi.nlm.nih.gov/pubmed/21579037
http://dx.doi.org/10.1107/S1600536810013553
work_keys_str_mv AT weixiaohong polydimethanolbism53pyridyltetrazolatok2n2n5copperii

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