2-Azido-2-de­oxy-3,4-O-isopropyl­idene-2-C-methyl-d-talono-1,5-lactone

The relative stereochemistry of the title compound, C(10)H(15)N(3)O(5), was confirmed by the crystal structure determin­ation. The absolute configuration was determined from the use of d-lyxonolactone as the starting material. The six-membered ring adopts a boat conformation with the larger azide gr...

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Detalles Bibliográficos
Autores principales: Jenkinson, Sarah F., Dai, Ni, Fleet, George W. J., Watkin, David J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979260/
https://www.ncbi.nlm.nih.gov/pubmed/21579248
http://dx.doi.org/10.1107/S160053681001500X
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author Jenkinson, Sarah F.
Dai, Ni
Fleet, George W. J.
Watkin, David J.
author_facet Jenkinson, Sarah F.
Dai, Ni
Fleet, George W. J.
Watkin, David J.
author_sort Jenkinson, Sarah F.
collection PubMed
description The relative stereochemistry of the title compound, C(10)H(15)N(3)O(5), was confirmed by the crystal structure determin­ation. The absolute configuration was determined from the use of d-lyxonolactone as the starting material. The six-membered ring adopts a boat conformation with the larger azide group, rather than the methyl group, in the bowsprit position. In the crystal structure, a bifurcated inter­molecular O—H⋯O/O—H⋯N hydrogen bond links mol­ecules into chains running parallel to the b axis.
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spelling pubmed-29792602010-12-30 2-Azido-2-de­oxy-3,4-O-isopropyl­idene-2-C-methyl-d-talono-1,5-lactone Jenkinson, Sarah F. Dai, Ni Fleet, George W. J. Watkin, David J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The relative stereochemistry of the title compound, C(10)H(15)N(3)O(5), was confirmed by the crystal structure determin­ation. The absolute configuration was determined from the use of d-lyxonolactone as the starting material. The six-membered ring adopts a boat conformation with the larger azide group, rather than the methyl group, in the bowsprit position. In the crystal structure, a bifurcated inter­molecular O—H⋯O/O—H⋯N hydrogen bond links mol­ecules into chains running parallel to the b axis. International Union of Crystallography 2010-04-30 /pmc/articles/PMC2979260/ /pubmed/21579248 http://dx.doi.org/10.1107/S160053681001500X Text en © Jenkinson et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jenkinson, Sarah F.
Dai, Ni
Fleet, George W. J.
Watkin, David J.
2-Azido-2-de­oxy-3,4-O-isopropyl­idene-2-C-methyl-d-talono-1,5-lactone
title 2-Azido-2-de­oxy-3,4-O-isopropyl­idene-2-C-methyl-d-talono-1,5-lactone
title_full 2-Azido-2-de­oxy-3,4-O-isopropyl­idene-2-C-methyl-d-talono-1,5-lactone
title_fullStr 2-Azido-2-de­oxy-3,4-O-isopropyl­idene-2-C-methyl-d-talono-1,5-lactone
title_full_unstemmed 2-Azido-2-de­oxy-3,4-O-isopropyl­idene-2-C-methyl-d-talono-1,5-lactone
title_short 2-Azido-2-de­oxy-3,4-O-isopropyl­idene-2-C-methyl-d-talono-1,5-lactone
title_sort 2-azido-2-de­oxy-3,4-o-isopropyl­idene-2-c-methyl-d-talono-1,5-lactone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979260/
https://www.ncbi.nlm.nih.gov/pubmed/21579248
http://dx.doi.org/10.1107/S160053681001500X
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