Dichlorido[2,3,5,6-tetra­fluoro-4-(tri­fluoro­meth­yl)phenyl-κC (1)]bis­(tri­methyl­phosphine-κP)cobalt(III)

In the title compound, [Co(C(7)F(7))Cl(2)(C(3)H(9)P)(2)], the Co(III) atom displays a trigonal–bipyramidal coordination geometry, with the two Cl ligands and the C atom of the perfluoro­tolyl ligand in the equatorial plane and the two phosphine ligands occupying axial positions. The mol­ecule has an...

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Detalles Bibliográficos
Autores principales: Zheng, Tingting, Sun, Hongjian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979265/
https://www.ncbi.nlm.nih.gov/pubmed/21579055
http://dx.doi.org/10.1107/S1600536810014066
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author Zheng, Tingting
Sun, Hongjian
author_facet Zheng, Tingting
Sun, Hongjian
author_sort Zheng, Tingting
collection PubMed
description In the title compound, [Co(C(7)F(7))Cl(2)(C(3)H(9)P)(2)], the Co(III) atom displays a trigonal–bipyramidal coordination geometry, with the two Cl ligands and the C atom of the perfluoro­tolyl ligand in the equatorial plane and the two phosphine ligands occupying axial positions. The mol­ecule has an approximate C (2v) symmetry. The trifluoro­methyl group is disordered over two positions, with nearly equal occupancies.
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spelling pubmed-29792652010-12-30 Dichlorido[2,3,5,6-tetra­fluoro-4-(tri­fluoro­meth­yl)phenyl-κC (1)]bis­(tri­methyl­phosphine-κP)cobalt(III) Zheng, Tingting Sun, Hongjian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(7)F(7))Cl(2)(C(3)H(9)P)(2)], the Co(III) atom displays a trigonal–bipyramidal coordination geometry, with the two Cl ligands and the C atom of the perfluoro­tolyl ligand in the equatorial plane and the two phosphine ligands occupying axial positions. The mol­ecule has an approximate C (2v) symmetry. The trifluoro­methyl group is disordered over two positions, with nearly equal occupancies. International Union of Crystallography 2010-04-24 /pmc/articles/PMC2979265/ /pubmed/21579055 http://dx.doi.org/10.1107/S1600536810014066 Text en © Zheng and Sun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zheng, Tingting
Sun, Hongjian
Dichlorido[2,3,5,6-tetra­fluoro-4-(tri­fluoro­meth­yl)phenyl-κC (1)]bis­(tri­methyl­phosphine-κP)cobalt(III)
title Dichlorido[2,3,5,6-tetra­fluoro-4-(tri­fluoro­meth­yl)phenyl-κC (1)]bis­(tri­methyl­phosphine-κP)cobalt(III)
title_full Dichlorido[2,3,5,6-tetra­fluoro-4-(tri­fluoro­meth­yl)phenyl-κC (1)]bis­(tri­methyl­phosphine-κP)cobalt(III)
title_fullStr Dichlorido[2,3,5,6-tetra­fluoro-4-(tri­fluoro­meth­yl)phenyl-κC (1)]bis­(tri­methyl­phosphine-κP)cobalt(III)
title_full_unstemmed Dichlorido[2,3,5,6-tetra­fluoro-4-(tri­fluoro­meth­yl)phenyl-κC (1)]bis­(tri­methyl­phosphine-κP)cobalt(III)
title_short Dichlorido[2,3,5,6-tetra­fluoro-4-(tri­fluoro­meth­yl)phenyl-κC (1)]bis­(tri­methyl­phosphine-κP)cobalt(III)
title_sort dichlorido[2,3,5,6-tetra­fluoro-4-(tri­fluoro­meth­yl)phenyl-κc (1)]bis­(tri­methyl­phosphine-κp)cobalt(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979265/
https://www.ncbi.nlm.nih.gov/pubmed/21579055
http://dx.doi.org/10.1107/S1600536810014066
work_keys_str_mv AT zhengtingting dichlorido2356tetrafluoro4trifluoromethylphenylkc1bistrimethylphosphinekpcobaltiii
AT sunhongjian dichlorido2356tetrafluoro4trifluoromethylphenylkc1bistrimethylphosphinekpcobaltiii

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