Di-μ-chlorido-bis­[chlorido(dimethoxy­phenyl­phosphine)palladium(II)]

The title compound, [Pd(2)Cl(4)(C(8)H(11)O(2)P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd⋯Pd distance of 3.4662 (17) Å. It has a similar geometry to that observed in the triphenyl­phosphite and triphenyl­phosphine analogues. The Pd—P bond length is ca 0.04 ...

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Detalles Bibliográficos
Autores principales: Slawin, Alexandra M. Z., Waddell, Paul G., Woollins, J. Derek
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979266/
https://www.ncbi.nlm.nih.gov/pubmed/21579000
http://dx.doi.org/10.1107/S1600536810012055
Descripción
Sumario:The title compound, [Pd(2)Cl(4)(C(8)H(11)O(2)P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd⋯Pd distance of 3.4662 (17) Å. It has a similar geometry to that observed in the triphenyl­phosphite and triphenyl­phosphine analogues. The Pd—P bond length is ca 0.04 Å shorter than those in mononuclear PdCl(2)(P(OMe)(2)Ph)(2), possibly due to the lower trans-influence of the bridging Cl(−) compared to a single-bonded Cl(−) atom.

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