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Di-μ-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)]
The title compound, [Pd(2)Cl(4)(C(8)H(11)O(2)P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd⋯Pd distance of 3.4662 (17) Å. It has a similar geometry to that observed in the triphenylphosphite and triphenylphosphine analogues. The Pd—P bond length is ca 0.04 ...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979266/ https://www.ncbi.nlm.nih.gov/pubmed/21579000 http://dx.doi.org/10.1107/S1600536810012055 |
| _version_ | 1782191382973120512 |
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| author | Slawin, Alexandra M. Z. Waddell, Paul G. Woollins, J. Derek |
| author_facet | Slawin, Alexandra M. Z. Waddell, Paul G. Woollins, J. Derek |
| author_sort | Slawin, Alexandra M. Z. |
| collection | PubMed |
| description | The title compound, [Pd(2)Cl(4)(C(8)H(11)O(2)P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd⋯Pd distance of 3.4662 (17) Å. It has a similar geometry to that observed in the triphenylphosphite and triphenylphosphine analogues. The Pd—P bond length is ca 0.04 Å shorter than those in mononuclear PdCl(2)(P(OMe)(2)Ph)(2), possibly due to the lower trans-influence of the bridging Cl(−) compared to a single-bonded Cl(−) atom. |
| format | Text |
| id | pubmed-2979266 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29792662010-12-30 Di-μ-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)] Slawin, Alexandra M. Z. Waddell, Paul G. Woollins, J. Derek Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(2)Cl(4)(C(8)H(11)O(2)P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd⋯Pd distance of 3.4662 (17) Å. It has a similar geometry to that observed in the triphenylphosphite and triphenylphosphine analogues. The Pd—P bond length is ca 0.04 Å shorter than those in mononuclear PdCl(2)(P(OMe)(2)Ph)(2), possibly due to the lower trans-influence of the bridging Cl(−) compared to a single-bonded Cl(−) atom. International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979266/ /pubmed/21579000 http://dx.doi.org/10.1107/S1600536810012055 Text en © Slawin et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Slawin, Alexandra M. Z. Waddell, Paul G. Woollins, J. Derek Di-μ-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)] |
| title | Di-μ-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)] |
| title_full | Di-μ-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)] |
| title_fullStr | Di-μ-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)] |
| title_full_unstemmed | Di-μ-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)] |
| title_short | Di-μ-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)] |
| title_sort | di-μ-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979266/ https://www.ncbi.nlm.nih.gov/pubmed/21579000 http://dx.doi.org/10.1107/S1600536810012055 |
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