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N′-[1-(2-Aminophenyl)ethylidene]benzohydrazide
The title compound, C(15)H(15)N(3)O, was obtained by a condensation reaction between o-aminoacetophenone and benzoyl hydrazine. The molecule displays an E configuration about the C=N bond. Intramolecular N—H⋯N hydrogen bonds are formed between the 2-aminophenyl and imine groups. In the crystal,...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979270/ https://www.ncbi.nlm.nih.gov/pubmed/21579213 http://dx.doi.org/10.1107/S1600536810010937 |
Sumario: | The title compound, C(15)H(15)N(3)O, was obtained by a condensation reaction between o-aminoacetophenone and benzoyl hydrazine. The molecule displays an E configuration about the C=N bond. Intramolecular N—H⋯N hydrogen bonds are formed between the 2-aminophenyl and imine groups. In the crystal, dimers are formed between molecules linked by intermolecular N—H⋯O hydrogen bonds from the 2-aminophenyl group. In addition there are intermolecular N—H⋯O hydrogen bonds between the amine and carbonyl groups of adjacent molecules. The molecule is twisted rather than planar due to a steric interaction between the central amide group and the two outer benzene rings. The dihedral angles between this central group and the two rings are 23.29 (9) and 24.96 (9)°. |
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