(E)-2,4-Dihydr­oxy-N′-(2-hydr­oxy-3-meth­oxy-5-nitro­benzyl­idene)benzohydrazide dihydrate

The asymmetric unit of the title compound, C(15)H(13)N(3)O(7)·2H(2)O, consists of a hydrazone mol­ecule and two solvent water mol­ecules. The mol­ecule adopts an E configuration with respect to the C=N bond. It is relatively planar, with a dihedral angle between the two benzene rings of 2.6 (1)°. Th...

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Detalles Bibliográficos
Autores principales: Han, You-Yue, Li, Yong-Hong, Zhao, Qiu-Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979277/
https://www.ncbi.nlm.nih.gov/pubmed/21579139
http://dx.doi.org/10.1107/S1600536810013000
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author Han, You-Yue
Li, Yong-Hong
Zhao, Qiu-Rong
author_facet Han, You-Yue
Li, Yong-Hong
Zhao, Qiu-Rong
author_sort Han, You-Yue
collection PubMed
description The asymmetric unit of the title compound, C(15)H(13)N(3)O(7)·2H(2)O, consists of a hydrazone mol­ecule and two solvent water mol­ecules. The mol­ecule adopts an E configuration with respect to the C=N bond. It is relatively planar, with a dihedral angle between the two benzene rings of 2.6 (1)°. There are intra­molecular O—H⋯N and O—H⋯O hydrogen bonds in the hydrazone mol­ecule. In the crystal structure, symmetry-related mol­ecules are linked through inter­molecular N—H⋯O and O—H⋯O hydrogen bonds to form a three-dimensional network.
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spelling pubmed-29792772010-12-30 (E)-2,4-Dihydr­oxy-N′-(2-hydr­oxy-3-meth­oxy-5-nitro­benzyl­idene)benzohydrazide dihydrate Han, You-Yue Li, Yong-Hong Zhao, Qiu-Rong Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(15)H(13)N(3)O(7)·2H(2)O, consists of a hydrazone mol­ecule and two solvent water mol­ecules. The mol­ecule adopts an E configuration with respect to the C=N bond. It is relatively planar, with a dihedral angle between the two benzene rings of 2.6 (1)°. There are intra­molecular O—H⋯N and O—H⋯O hydrogen bonds in the hydrazone mol­ecule. In the crystal structure, symmetry-related mol­ecules are linked through inter­molecular N—H⋯O and O—H⋯O hydrogen bonds to form a three-dimensional network. International Union of Crystallography 2010-04-14 /pmc/articles/PMC2979277/ /pubmed/21579139 http://dx.doi.org/10.1107/S1600536810013000 Text en © Han et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Han, You-Yue
Li, Yong-Hong
Zhao, Qiu-Rong
(E)-2,4-Dihydr­oxy-N′-(2-hydr­oxy-3-meth­oxy-5-nitro­benzyl­idene)benzohydrazide dihydrate
title (E)-2,4-Dihydr­oxy-N′-(2-hydr­oxy-3-meth­oxy-5-nitro­benzyl­idene)benzohydrazide dihydrate
title_full (E)-2,4-Dihydr­oxy-N′-(2-hydr­oxy-3-meth­oxy-5-nitro­benzyl­idene)benzohydrazide dihydrate
title_fullStr (E)-2,4-Dihydr­oxy-N′-(2-hydr­oxy-3-meth­oxy-5-nitro­benzyl­idene)benzohydrazide dihydrate
title_full_unstemmed (E)-2,4-Dihydr­oxy-N′-(2-hydr­oxy-3-meth­oxy-5-nitro­benzyl­idene)benzohydrazide dihydrate
title_short (E)-2,4-Dihydr­oxy-N′-(2-hydr­oxy-3-meth­oxy-5-nitro­benzyl­idene)benzohydrazide dihydrate
title_sort (e)-2,4-dihydr­oxy-n′-(2-hydr­oxy-3-meth­oxy-5-nitro­benzyl­idene)benzohydrazide dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979277/
https://www.ncbi.nlm.nih.gov/pubmed/21579139
http://dx.doi.org/10.1107/S1600536810013000
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AT zhaoqiurong e24dihydroxyn2hydroxy3methoxy5nitrobenzylidenebenzohydrazidedihydrate

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