(4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidocadmium(II)

In the title compound, [CdI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Cd(II) cation is coordinated by two N atoms from a dimethyl­bipyridine ligand, one O atom from a dimethyl sulfoxide mol­ecule and two I(−) anions in a distorted trigonal–bipyramidal geometry. Intra­molecular C—H⋯O hydrogen bonding and...

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Detalles Bibliográficos
Autores principales: Kalateh, Khadijeh, Ahmadi, Roya, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979279/
https://www.ncbi.nlm.nih.gov/pubmed/21579009
http://dx.doi.org/10.1107/S1600536810012572
Descripción
Sumario:In the title compound, [CdI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Cd(II) cation is coordinated by two N atoms from a dimethyl­bipyridine ligand, one O atom from a dimethyl sulfoxide mol­ecule and two I(−) anions in a distorted trigonal–bipyramidal geometry. Intra­molecular C—H⋯O hydrogen bonding and inter­molecular π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.658 (3) Å] are present in the crystal structure.

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