(4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidocadmium(II)

In the title compound, [CdI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Cd(II) cation is coordinated by two N atoms from a dimethyl­bipyridine ligand, one O atom from a dimethyl sulfoxide mol­ecule and two I(−) anions in a distorted trigonal–bipyramidal geometry. Intra­molecular C—H⋯O hydrogen bonding and...

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Detalles Bibliográficos
Autores principales: Kalateh, Khadijeh, Ahmadi, Roya, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979279/
https://www.ncbi.nlm.nih.gov/pubmed/21579009
http://dx.doi.org/10.1107/S1600536810012572
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author Kalateh, Khadijeh
Ahmadi, Roya
Amani, Vahid
author_facet Kalateh, Khadijeh
Ahmadi, Roya
Amani, Vahid
author_sort Kalateh, Khadijeh
collection PubMed
description In the title compound, [CdI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Cd(II) cation is coordinated by two N atoms from a dimethyl­bipyridine ligand, one O atom from a dimethyl sulfoxide mol­ecule and two I(−) anions in a distorted trigonal–bipyramidal geometry. Intra­molecular C—H⋯O hydrogen bonding and inter­molecular π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.658 (3) Å] are present in the crystal structure.
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spelling pubmed-29792792010-12-30 (4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidocadmium(II) Kalateh, Khadijeh Ahmadi, Roya Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CdI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Cd(II) cation is coordinated by two N atoms from a dimethyl­bipyridine ligand, one O atom from a dimethyl sulfoxide mol­ecule and two I(−) anions in a distorted trigonal–bipyramidal geometry. Intra­molecular C—H⋯O hydrogen bonding and inter­molecular π–π stacking between parallel pyridine rings [centroid–centroid distance = 3.658 (3) Å] are present in the crystal structure. International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979279/ /pubmed/21579009 http://dx.doi.org/10.1107/S1600536810012572 Text en © Kalateh et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kalateh, Khadijeh
Ahmadi, Roya
Amani, Vahid
(4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidocadmium(II)
title (4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidocadmium(II)
title_full (4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidocadmium(II)
title_fullStr (4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidocadmium(II)
title_full_unstemmed (4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidocadmium(II)
title_short (4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidocadmium(II)
title_sort (4,4′-dimethyl-2,2′-bipyridine-κ(2) n,n′)(dimethyl sulfoxide-κo)diiodidocadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979279/
https://www.ncbi.nlm.nih.gov/pubmed/21579009
http://dx.doi.org/10.1107/S1600536810012572
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AT ahmadiroya 44dimethyl22bipyridinek2nndimethylsulfoxidekodiiodidocadmiumii
AT amanivahid 44dimethyl22bipyridinek2nndimethylsulfoxidekodiiodidocadmiumii

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