2-(4-Morpholine­carbothio­ylsulfan­yl)­acetic acid

The asymmetric unit of the title compound, C(7)H(11)NO(3)S(2), contains two independent mol­ecules with similar mol­ecular structures. The morpholine ring adopts a chair conformation, and the C(2)N—C(=S)—S fragment is planar in the two independent mol­ecules (r.m.s. deviations = 0.01 and 0.02 Å). Th...

Descripción completa

Detalles Bibliográficos
Autores principales: Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979280/
https://www.ncbi.nlm.nih.gov/pubmed/21579132
http://dx.doi.org/10.1107/S1600536810012602
Descripción
Sumario:The asymmetric unit of the title compound, C(7)H(11)NO(3)S(2), contains two independent mol­ecules with similar mol­ecular structures. The morpholine ring adopts a chair conformation, and the C(2)N—C(=S)—S fragment is planar in the two independent mol­ecules (r.m.s. deviations = 0.01 and 0.02 Å). The two mol­ecules are disposed about a false center of inversion and are held together by a pair of O—H⋯O hydrogen bonds. The crystal studied was a racemic twin; the minor twin component refined to 17%.

Ejemplares similares