N′-Acetyl-5-amino-1-methyl-1H-pyrazole-4-carbohydrazonamide dihydrate

In the title compound, C(7)H(12)N(6)O·2H(2)O, the Z configuration of the hydrazone fragment is stabilized by an intra­molecular N—H⋯N hydrogen bond involving one of the amino groups. In the crystal structure, the hydrazonamide mol­ecules are connected via inter­molecular N—H⋯O=C hydrogen bonds, form...

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Autores principales: Dolzhenko, Anna V., Dolzhenko, Anton V., Tan, Geok Kheng, Koh, Lip Lin, Pastorin, Giorgia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979283/
https://www.ncbi.nlm.nih.gov/pubmed/21579239
http://dx.doi.org/10.1107/S1600536810015357
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author Dolzhenko, Anna V.
Dolzhenko, Anton V.
Tan, Geok Kheng
Koh, Lip Lin
Pastorin, Giorgia
author_facet Dolzhenko, Anna V.
Dolzhenko, Anton V.
Tan, Geok Kheng
Koh, Lip Lin
Pastorin, Giorgia
author_sort Dolzhenko, Anna V.
collection PubMed
description In the title compound, C(7)H(12)N(6)O·2H(2)O, the Z configuration of the hydrazone fragment is stabilized by an intra­molecular N—H⋯N hydrogen bond involving one of the amino groups. In the crystal structure, the hydrazonamide mol­ecules are connected via inter­molecular N—H⋯O=C hydrogen bonds, forming C(7) chains running along [010]. The chains form sheets parallel to the ([Image: see text]01). The chains are cross-linked by water mol­ecules to form a three-dimensional hydrogen-bonded network.
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spelling pubmed-29792832010-12-30 N′-Acetyl-5-amino-1-methyl-1H-pyrazole-4-carbohydrazonamide dihydrate Dolzhenko, Anna V. Dolzhenko, Anton V. Tan, Geok Kheng Koh, Lip Lin Pastorin, Giorgia Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(12)N(6)O·2H(2)O, the Z configuration of the hydrazone fragment is stabilized by an intra­molecular N—H⋯N hydrogen bond involving one of the amino groups. In the crystal structure, the hydrazonamide mol­ecules are connected via inter­molecular N—H⋯O=C hydrogen bonds, forming C(7) chains running along [010]. The chains form sheets parallel to the ([Image: see text]01). The chains are cross-linked by water mol­ecules to form a three-dimensional hydrogen-bonded network. International Union of Crystallography 2010-04-30 /pmc/articles/PMC2979283/ /pubmed/21579239 http://dx.doi.org/10.1107/S1600536810015357 Text en © Dolzhenko et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dolzhenko, Anna V.
Dolzhenko, Anton V.
Tan, Geok Kheng
Koh, Lip Lin
Pastorin, Giorgia
N′-Acetyl-5-amino-1-methyl-1H-pyrazole-4-carbohydrazonamide dihydrate
title N′-Acetyl-5-amino-1-methyl-1H-pyrazole-4-carbohydrazonamide dihydrate
title_full N′-Acetyl-5-amino-1-methyl-1H-pyrazole-4-carbohydrazonamide dihydrate
title_fullStr N′-Acetyl-5-amino-1-methyl-1H-pyrazole-4-carbohydrazonamide dihydrate
title_full_unstemmed N′-Acetyl-5-amino-1-methyl-1H-pyrazole-4-carbohydrazonamide dihydrate
title_short N′-Acetyl-5-amino-1-methyl-1H-pyrazole-4-carbohydrazonamide dihydrate
title_sort n′-acetyl-5-amino-1-methyl-1h-pyrazole-4-carbohydrazonamide dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979283/
https://www.ncbi.nlm.nih.gov/pubmed/21579239
http://dx.doi.org/10.1107/S1600536810015357
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