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Tetraaquabis[4-(methylamino)benzoato-κO]nickel(II)
The title complex, [Ni(C(8)H(8)NO(2))(2)(H(2)O)(4)], is centrosymmetric with the Ni(II) ion located on a centre of symmetry. It contains two 4-(methylamino)benzoate (PMAB) anions and four coordinated water molecules. The four O atoms in the equatorial plane around the Ni(II) ion form a slightly di...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979289/ https://www.ncbi.nlm.nih.gov/pubmed/21579062 http://dx.doi.org/10.1107/S1600536810014807 |
Sumario: | The title complex, [Ni(C(8)H(8)NO(2))(2)(H(2)O)(4)], is centrosymmetric with the Ni(II) ion located on a centre of symmetry. It contains two 4-(methylamino)benzoate (PMAB) anions and four coordinated water molecules. The four O atoms in the equatorial plane around the Ni(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by two O atoms of the PMAB anions in the axial positions. In the crystal structure, intermolecular O—H⋯O, O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds link the molecules into a three-dimensional network. |
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