Tetra­aqua­bis[4-(methyl­amino)benzoato-κO]nickel(II)

The title complex, [Ni(C(8)H(8)NO(2))(2)(H(2)O)(4)], is centrosymmetric with the Ni(II) ion located on a centre of symmetry. It contains two 4-(methyl­amino)benzoate (PMAB) anions and four coordinated water mol­ecules. The four O atoms in the equatorial plane around the Ni(II) ion form a slightly di...

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Detalles Bibliográficos
Autores principales: Necefoğlu, Hacali, Aybirdi, Özgür, Tercan, Barış, Süzen, Yasemin, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979289/
https://www.ncbi.nlm.nih.gov/pubmed/21579062
http://dx.doi.org/10.1107/S1600536810014807
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author Necefoğlu, Hacali
Aybirdi, Özgür
Tercan, Barış
Süzen, Yasemin
Hökelek, Tuncer
author_facet Necefoğlu, Hacali
Aybirdi, Özgür
Tercan, Barış
Süzen, Yasemin
Hökelek, Tuncer
author_sort Necefoğlu, Hacali
collection PubMed
description The title complex, [Ni(C(8)H(8)NO(2))(2)(H(2)O)(4)], is centrosymmetric with the Ni(II) ion located on a centre of symmetry. It contains two 4-(methyl­amino)benzoate (PMAB) anions and four coordinated water mol­ecules. The four O atoms in the equatorial plane around the Ni(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by two O atoms of the PMAB anions in the axial positions. In the crystal structure, inter­molecular O—H⋯O, O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network.
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spelling pubmed-29792892010-12-30 Tetra­aqua­bis[4-(methyl­amino)benzoato-κO]nickel(II) Necefoğlu, Hacali Aybirdi, Özgür Tercan, Barış Süzen, Yasemin Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ni(C(8)H(8)NO(2))(2)(H(2)O)(4)], is centrosymmetric with the Ni(II) ion located on a centre of symmetry. It contains two 4-(methyl­amino)benzoate (PMAB) anions and four coordinated water mol­ecules. The four O atoms in the equatorial plane around the Ni(II) ion form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by two O atoms of the PMAB anions in the axial positions. In the crystal structure, inter­molecular O—H⋯O, O—H⋯N, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. International Union of Crystallography 2010-04-28 /pmc/articles/PMC2979289/ /pubmed/21579062 http://dx.doi.org/10.1107/S1600536810014807 Text en © Necefoğlu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Necefoğlu, Hacali
Aybirdi, Özgür
Tercan, Barış
Süzen, Yasemin
Hökelek, Tuncer
Tetra­aqua­bis[4-(methyl­amino)benzoato-κO]nickel(II)
title Tetra­aqua­bis[4-(methyl­amino)benzoato-κO]nickel(II)
title_full Tetra­aqua­bis[4-(methyl­amino)benzoato-κO]nickel(II)
title_fullStr Tetra­aqua­bis[4-(methyl­amino)benzoato-κO]nickel(II)
title_full_unstemmed Tetra­aqua­bis[4-(methyl­amino)benzoato-κO]nickel(II)
title_short Tetra­aqua­bis[4-(methyl­amino)benzoato-κO]nickel(II)
title_sort tetra­aqua­bis[4-(methyl­amino)benzoato-κo]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979289/
https://www.ncbi.nlm.nih.gov/pubmed/21579062
http://dx.doi.org/10.1107/S1600536810014807
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AT aybirdiozgur tetraaquabis4methylaminobenzoatokonickelii
AT tercanbarıs tetraaquabis4methylaminobenzoatokonickelii
AT suzenyasemin tetraaquabis4methylaminobenzoatokonickelii
AT hokelektuncer tetraaquabis4methylaminobenzoatokonickelii

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