Tris[2-(1H-imidazol-2-yl)imidazol-1-ido]cobalt(III)

In the title compound, [Co(C(6)H(5)N(4))(3)], the Co(III) atom adopts a distorted octa­hedral CoN(6) coordination geometry, arising from three N,N′-bidentate deprotonated 2,2′-biimidazole ligands. The dihedral angles between the five-membered rings of the ligands are 4.1 (2), 9.4 (2) and 10.5 (2)°....

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Detalles Bibliográficos
Autores principales: Ma, Qi, Zhu, Miaoli, Feng, Sisi, Lu, Liping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979296/
https://www.ncbi.nlm.nih.gov/pubmed/21579001
http://dx.doi.org/10.1107/S1600536810011785
Descripción
Sumario:In the title compound, [Co(C(6)H(5)N(4))(3)], the Co(III) atom adopts a distorted octa­hedral CoN(6) coordination geometry, arising from three N,N′-bidentate deprotonated 2,2′-biimidazole ligands. The dihedral angles between the five-membered rings of the ligands are 4.1 (2), 9.4 (2) and 10.5 (2)°. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds, generating a layered network lying in (11[Image: see text]).

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