Tris[2-(1H-imidazol-2-yl)imidazol-1-ido]cobalt(III)

In the title compound, [Co(C(6)H(5)N(4))(3)], the Co(III) atom adopts a distorted octa­hedral CoN(6) coordination geometry, arising from three N,N′-bidentate deprotonated 2,2′-biimidazole ligands. The dihedral angles between the five-membered rings of the ligands are 4.1 (2), 9.4 (2) and 10.5 (2)°....

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Detalles Bibliográficos
Autores principales: Ma, Qi, Zhu, Miaoli, Feng, Sisi, Lu, Liping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979296/
https://www.ncbi.nlm.nih.gov/pubmed/21579001
http://dx.doi.org/10.1107/S1600536810011785
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author Ma, Qi
Zhu, Miaoli
Feng, Sisi
Lu, Liping
author_facet Ma, Qi
Zhu, Miaoli
Feng, Sisi
Lu, Liping
author_sort Ma, Qi
collection PubMed
description In the title compound, [Co(C(6)H(5)N(4))(3)], the Co(III) atom adopts a distorted octa­hedral CoN(6) coordination geometry, arising from three N,N′-bidentate deprotonated 2,2′-biimidazole ligands. The dihedral angles between the five-membered rings of the ligands are 4.1 (2), 9.4 (2) and 10.5 (2)°. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds, generating a layered network lying in (11[Image: see text]).
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spelling pubmed-29792962010-12-30 Tris[2-(1H-imidazol-2-yl)imidazol-1-ido]cobalt(III) Ma, Qi Zhu, Miaoli Feng, Sisi Lu, Liping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(6)H(5)N(4))(3)], the Co(III) atom adopts a distorted octa­hedral CoN(6) coordination geometry, arising from three N,N′-bidentate deprotonated 2,2′-biimidazole ligands. The dihedral angles between the five-membered rings of the ligands are 4.1 (2), 9.4 (2) and 10.5 (2)°. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds, generating a layered network lying in (11[Image: see text]). International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979296/ /pubmed/21579001 http://dx.doi.org/10.1107/S1600536810011785 Text en © Ma et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Qi
Zhu, Miaoli
Feng, Sisi
Lu, Liping
Tris[2-(1H-imidazol-2-yl)imidazol-1-ido]cobalt(III)
title Tris[2-(1H-imidazol-2-yl)imidazol-1-ido]cobalt(III)
title_full Tris[2-(1H-imidazol-2-yl)imidazol-1-ido]cobalt(III)
title_fullStr Tris[2-(1H-imidazol-2-yl)imidazol-1-ido]cobalt(III)
title_full_unstemmed Tris[2-(1H-imidazol-2-yl)imidazol-1-ido]cobalt(III)
title_short Tris[2-(1H-imidazol-2-yl)imidazol-1-ido]cobalt(III)
title_sort tris[2-(1h-imidazol-2-yl)imidazol-1-ido]cobalt(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979296/
https://www.ncbi.nlm.nih.gov/pubmed/21579001
http://dx.doi.org/10.1107/S1600536810011785
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AT zhumiaoli tris21himidazol2ylimidazol1idocobaltiii
AT fengsisi tris21himidazol2ylimidazol1idocobaltiii
AT luliping tris21himidazol2ylimidazol1idocobaltiii

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