Bis(propane-1,3-diaminium) hexa­fluoridoferrate(III) fluoride trihydrate

The asymmetric unit of the title iron hybrid fluoride, (C(3)H(12)N(2))(2)[FeF(6)]F·3H(2)O, contains two propane-1,3-diamin­ium [(H(2)dap)(2+)] cations, an octa­hedral [FeF(6)](3−) anion, an isolated F(−) anion and three water mol­ecules of solvation. Each [FeF(6)](3−) anion is surrounded by four sep...

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Detalles Bibliográficos
Autores principales: Zouaghi, Aymen, BenAli, Amor, Maisonneuve, Vincent, Leblanc, Marc
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979354/
https://www.ncbi.nlm.nih.gov/pubmed/21579337
http://dx.doi.org/10.1107/S1600536810018039
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author Zouaghi, Aymen
BenAli, Amor
Maisonneuve, Vincent
Leblanc, Marc
author_facet Zouaghi, Aymen
BenAli, Amor
Maisonneuve, Vincent
Leblanc, Marc
author_sort Zouaghi, Aymen
collection PubMed
description The asymmetric unit of the title iron hybrid fluoride, (C(3)H(12)N(2))(2)[FeF(6)]F·3H(2)O, contains two propane-1,3-diamin­ium [(H(2)dap)(2+)] cations, an octa­hedral [FeF(6)](3−) anion, an isolated F(−) anion and three water mol­ecules of solvation. Each [FeF(6)](3−) anion is surrounded by four separate hydrogen-bonded water mol­ecules in the equatorial sites and by five separate aminium cation donor groups. The axial F atoms are only involved in N—H⋯F hydrogen bonds, resulting in a three-dimensional structure.
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spelling pubmed-29793542010-12-30 Bis(propane-1,3-diaminium) hexa­fluoridoferrate(III) fluoride trihydrate Zouaghi, Aymen BenAli, Amor Maisonneuve, Vincent Leblanc, Marc Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title iron hybrid fluoride, (C(3)H(12)N(2))(2)[FeF(6)]F·3H(2)O, contains two propane-1,3-diamin­ium [(H(2)dap)(2+)] cations, an octa­hedral [FeF(6)](3−) anion, an isolated F(−) anion and three water mol­ecules of solvation. Each [FeF(6)](3−) anion is surrounded by four separate hydrogen-bonded water mol­ecules in the equatorial sites and by five separate aminium cation donor groups. The axial F atoms are only involved in N—H⋯F hydrogen bonds, resulting in a three-dimensional structure. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979354/ /pubmed/21579337 http://dx.doi.org/10.1107/S1600536810018039 Text en © Zouaghi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zouaghi, Aymen
BenAli, Amor
Maisonneuve, Vincent
Leblanc, Marc
Bis(propane-1,3-diaminium) hexa­fluoridoferrate(III) fluoride trihydrate
title Bis(propane-1,3-diaminium) hexa­fluoridoferrate(III) fluoride trihydrate
title_full Bis(propane-1,3-diaminium) hexa­fluoridoferrate(III) fluoride trihydrate
title_fullStr Bis(propane-1,3-diaminium) hexa­fluoridoferrate(III) fluoride trihydrate
title_full_unstemmed Bis(propane-1,3-diaminium) hexa­fluoridoferrate(III) fluoride trihydrate
title_short Bis(propane-1,3-diaminium) hexa­fluoridoferrate(III) fluoride trihydrate
title_sort bis(propane-1,3-diaminium) hexa­fluoridoferrate(iii) fluoride trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979354/
https://www.ncbi.nlm.nih.gov/pubmed/21579337
http://dx.doi.org/10.1107/S1600536810018039
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AT maisonneuvevincent bispropane13diaminiumhexafluoridoferrateiiifluoridetrihydrate
AT leblancmarc bispropane13diaminiumhexafluoridoferrateiiifluoridetrihydrate

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