Tetra­imidazole­bis(trichloro­acetato)copper(II)

The title compound, [Cu(C(2)Cl(3)O(2))(2)(C(3)H(4)N(2))(4)], was prepared by the reaction of imidazole and trichloro­acetatocopper(II). The Cu(II) atom adopts a distorted octa­hedral coordination geometry, binding the N atoms of four imidazole ligands and the carboxyl­ate O atoms of two trichloro­ac...

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Autores principales: Li, Li-Min, Guo, Huan-Mei, Jian, Fang-Fang, Zhang, Zeng-Hui, Zhang, Ning
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979359/
https://www.ncbi.nlm.nih.gov/pubmed/21579322
http://dx.doi.org/10.1107/S1600536810017459
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author Li, Li-Min
Guo, Huan-Mei
Jian, Fang-Fang
Zhang, Zeng-Hui
Zhang, Ning
author_facet Li, Li-Min
Guo, Huan-Mei
Jian, Fang-Fang
Zhang, Zeng-Hui
Zhang, Ning
author_sort Li, Li-Min
collection PubMed
description The title compound, [Cu(C(2)Cl(3)O(2))(2)(C(3)H(4)N(2))(4)], was prepared by the reaction of imidazole and trichloro­acetatocopper(II). The Cu(II) atom adopts a distorted octa­hedral coordination geometry, binding the N atoms of four imidazole ligands and the carboxyl­ate O atoms of two trichloro­acetate anions. The mol­ecular structure and packing are stabilized by N—H⋯O hydrogen-bonding inter­actions. Close inter­molecular Cl⋯Cl contacts [3.498 (3) Å] are also found in the structure.
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spelling pubmed-29793592010-12-30 Tetra­imidazole­bis(trichloro­acetato)copper(II) Li, Li-Min Guo, Huan-Mei Jian, Fang-Fang Zhang, Zeng-Hui Zhang, Ning Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(2)Cl(3)O(2))(2)(C(3)H(4)N(2))(4)], was prepared by the reaction of imidazole and trichloro­acetatocopper(II). The Cu(II) atom adopts a distorted octa­hedral coordination geometry, binding the N atoms of four imidazole ligands and the carboxyl­ate O atoms of two trichloro­acetate anions. The mol­ecular structure and packing are stabilized by N—H⋯O hydrogen-bonding inter­actions. Close inter­molecular Cl⋯Cl contacts [3.498 (3) Å] are also found in the structure. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979359/ /pubmed/21579322 http://dx.doi.org/10.1107/S1600536810017459 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Li-Min
Guo, Huan-Mei
Jian, Fang-Fang
Zhang, Zeng-Hui
Zhang, Ning
Tetra­imidazole­bis(trichloro­acetato)copper(II)
title Tetra­imidazole­bis(trichloro­acetato)copper(II)
title_full Tetra­imidazole­bis(trichloro­acetato)copper(II)
title_fullStr Tetra­imidazole­bis(trichloro­acetato)copper(II)
title_full_unstemmed Tetra­imidazole­bis(trichloro­acetato)copper(II)
title_short Tetra­imidazole­bis(trichloro­acetato)copper(II)
title_sort tetra­imidazole­bis(trichloro­acetato)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979359/
https://www.ncbi.nlm.nih.gov/pubmed/21579322
http://dx.doi.org/10.1107/S1600536810017459
work_keys_str_mv AT lilimin tetraimidazolebistrichloroacetatocopperii
AT guohuanmei tetraimidazolebistrichloroacetatocopperii
AT jianfangfang tetraimidazolebistrichloroacetatocopperii
AT zhangzenghui tetraimidazolebistrichloroacetatocopperii
AT zhangning tetraimidazolebistrichloroacetatocopperii

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