(E)-N′-(2-Benzyl­oxybenzyl­idene)isonicotinohydrazide methanol solvate monohydrate

The title compound, C(20)H(17)N(3)O(2)·CH(4)O·H(2)O, was synthesized by the condensation reaction of 2-benzyl­oxybenzaldehyde with isoniazid (isonicotinic acid hydrazide). The tricyclic compound displays a trans configuration with respect to the C=N double bond. The central benzene ring makes dihedr...

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Detalles Bibliográficos
Autores principales: Naveenkumar, H. S., Sadikun, Amirin, Ibrahim, Pazilah, Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979361/
https://www.ncbi.nlm.nih.gov/pubmed/21579427
http://dx.doi.org/10.1107/S1600536810016958
Descripción
Sumario:The title compound, C(20)H(17)N(3)O(2)·CH(4)O·H(2)O, was synthesized by the condensation reaction of 2-benzyl­oxybenzaldehyde with isoniazid (isonicotinic acid hydrazide). The tricyclic compound displays a trans configuration with respect to the C=N double bond. The central benzene ring makes dihedral angles of 8.83 (7) and 70.39 (8)° with the pyridine ring and the terminal benzene ring, respectively. The dihedral angle between the pyridine ring and the terminal benzene ring is 73.11 (8)°. In the crystal structure, mol­ecules are connected by inter­molecular N—H⋯O, O—H⋯O, O—H⋯(N,N) and C—H⋯O hydrogen bonds, forming a two-dimensional network perpendicular to the a axis.

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