Cargando…
Di-μ(1,1)-azido-bis[(2-{1-[2-(isopropylamino)ethylimino]ethyl}phenolato)copper(II)]
In the centrosymmetric binuclear title complex, [Cu(2)(C(13)H(19)N(2)O)(2)(N(3))(2)], the Cu(II) atom adopts an elongated CuON(4) square-based pyramidal coordination geometry, arising from the N,N′,O-tridentate ligand and two bridging end-on azide anions. The O atom is in the basal plane, one of the...
| Autor principal: | |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979365/ https://www.ncbi.nlm.nih.gov/pubmed/21579298 http://dx.doi.org/10.1107/S1600536810017174 |
| _version_ | 1782191395154427904 |
|---|---|
| author | Li, He-Bing |
| author_facet | Li, He-Bing |
| author_sort | Li, He-Bing |
| collection | PubMed |
| description | In the centrosymmetric binuclear title complex, [Cu(2)(C(13)H(19)N(2)O)(2)(N(3))(2)], the Cu(II) atom adopts an elongated CuON(4) square-based pyramidal coordination geometry, arising from the N,N′,O-tridentate ligand and two bridging end-on azide anions. The O atom is in the basal plane, one of the azide N atoms is in the apical site and the Cu⋯Cu separation is 3.2365 (3) Å. A pair of intramolecular N—H⋯O hydrogen bonds helps to establish the molecular conformation. |
| format | Text |
| id | pubmed-2979365 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29793652010-12-30 Di-μ(1,1)-azido-bis[(2-{1-[2-(isopropylamino)ethylimino]ethyl}phenolato)copper(II)] Li, He-Bing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric binuclear title complex, [Cu(2)(C(13)H(19)N(2)O)(2)(N(3))(2)], the Cu(II) atom adopts an elongated CuON(4) square-based pyramidal coordination geometry, arising from the N,N′,O-tridentate ligand and two bridging end-on azide anions. The O atom is in the basal plane, one of the azide N atoms is in the apical site and the Cu⋯Cu separation is 3.2365 (3) Å. A pair of intramolecular N—H⋯O hydrogen bonds helps to establish the molecular conformation. International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979365/ /pubmed/21579298 http://dx.doi.org/10.1107/S1600536810017174 Text en © He-Bing Li 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Li, He-Bing Di-μ(1,1)-azido-bis[(2-{1-[2-(isopropylamino)ethylimino]ethyl}phenolato)copper(II)] |
| title | Di-μ(1,1)-azido-bis[(2-{1-[2-(isopropylamino)ethylimino]ethyl}phenolato)copper(II)] |
| title_full | Di-μ(1,1)-azido-bis[(2-{1-[2-(isopropylamino)ethylimino]ethyl}phenolato)copper(II)] |
| title_fullStr | Di-μ(1,1)-azido-bis[(2-{1-[2-(isopropylamino)ethylimino]ethyl}phenolato)copper(II)] |
| title_full_unstemmed | Di-μ(1,1)-azido-bis[(2-{1-[2-(isopropylamino)ethylimino]ethyl}phenolato)copper(II)] |
| title_short | Di-μ(1,1)-azido-bis[(2-{1-[2-(isopropylamino)ethylimino]ethyl}phenolato)copper(II)] |
| title_sort | di-μ(1,1)-azido-bis[(2-{1-[2-(isopropylamino)ethylimino]ethyl}phenolato)copper(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979365/ https://www.ncbi.nlm.nih.gov/pubmed/21579298 http://dx.doi.org/10.1107/S1600536810017174 |
| work_keys_str_mv | AT lihebing dim11azidobis212isopropylaminoethyliminoethylphenolatocopperii |