Bis{1,2-bis­[bis­(3-hydroxy­prop­yl)phosphino]ethane}dichloridoiron(II)

In the title compound, [FeCl(2)(C(14)H(32)O(4)P(2))(2)], the Fe(II) atom (site symmetry [Image: see text]) adopts a distorted trans-FeCl(2)P(4) octa­hedral geometry with two P,P′-bidentate ligands in the equatorial positions and two chloride ions in the axial positions. In the crystal, mol­ecules ar...

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Detalles Bibliográficos
Autores principales: Crossland, Justin L., Zakharov, Lev N., Tyler, David R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979366/
https://www.ncbi.nlm.nih.gov/pubmed/21579318
http://dx.doi.org/10.1107/S160053681001768X
Descripción
Sumario:In the title compound, [FeCl(2)(C(14)H(32)O(4)P(2))(2)], the Fe(II) atom (site symmetry [Image: see text]) adopts a distorted trans-FeCl(2)P(4) octa­hedral geometry with two P,P′-bidentate ligands in the equatorial positions and two chloride ions in the axial positions. In the crystal, mol­ecules are linked by O—H⋯O and O—H⋯Cl hydrogen bonds, generating a three-dimensional network.

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