Tetra­aqua­bis(orotato-κO)cobalt(II) dihydrate

In the title Co(II) complex, [Co(C(5)H(3)N(2)O(4))(2)(H(2)O)(4)]·2H(2)O, the Co(II) ion is located on an inversion center and is coordinated by two orotate (2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylate) anions and four water mol­ecules in a slightly distorted octa­hedral geometry. The dihedr...

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Autores principales: Ay, Ahmet Nedim, Köse, Dursun Ali, Tercan, Barış, Yüksel, Fatma, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979368/
https://www.ncbi.nlm.nih.gov/pubmed/21579272
http://dx.doi.org/10.1107/S1600536810015837
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author Ay, Ahmet Nedim
Köse, Dursun Ali
Tercan, Barış
Yüksel, Fatma
Hökelek, Tuncer
author_facet Ay, Ahmet Nedim
Köse, Dursun Ali
Tercan, Barış
Yüksel, Fatma
Hökelek, Tuncer
author_sort Ay, Ahmet Nedim
collection PubMed
description In the title Co(II) complex, [Co(C(5)H(3)N(2)O(4))(2)(H(2)O)(4)]·2H(2)O, the Co(II) ion is located on an inversion center and is coordinated by two orotate (2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylate) anions and four water mol­ecules in a slightly distorted octa­hedral geometry. The dihedral angle between the carboxyl­ate group and the attached orotate ring is 1.2 (3)°. In the crystal structure, inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. π–π contacts between the orotate rings [centroid–centroid distances = 3.439 (2) and 3.438 (2) Å] further stabilize the structure.
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spelling pubmed-29793682010-12-30 Tetra­aqua­bis(orotato-κO)cobalt(II) dihydrate Ay, Ahmet Nedim Köse, Dursun Ali Tercan, Barış Yüksel, Fatma Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Co(II) complex, [Co(C(5)H(3)N(2)O(4))(2)(H(2)O)(4)]·2H(2)O, the Co(II) ion is located on an inversion center and is coordinated by two orotate (2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylate) anions and four water mol­ecules in a slightly distorted octa­hedral geometry. The dihedral angle between the carboxyl­ate group and the attached orotate ring is 1.2 (3)°. In the crystal structure, inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network. π–π contacts between the orotate rings [centroid–centroid distances = 3.439 (2) and 3.438 (2) Å] further stabilize the structure. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979368/ /pubmed/21579272 http://dx.doi.org/10.1107/S1600536810015837 Text en © Ay et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ay, Ahmet Nedim
Köse, Dursun Ali
Tercan, Barış
Yüksel, Fatma
Hökelek, Tuncer
Tetra­aqua­bis(orotato-κO)cobalt(II) dihydrate
title Tetra­aqua­bis(orotato-κO)cobalt(II) dihydrate
title_full Tetra­aqua­bis(orotato-κO)cobalt(II) dihydrate
title_fullStr Tetra­aqua­bis(orotato-κO)cobalt(II) dihydrate
title_full_unstemmed Tetra­aqua­bis(orotato-κO)cobalt(II) dihydrate
title_short Tetra­aqua­bis(orotato-κO)cobalt(II) dihydrate
title_sort tetra­aqua­bis(orotato-κo)cobalt(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979368/
https://www.ncbi.nlm.nih.gov/pubmed/21579272
http://dx.doi.org/10.1107/S1600536810015837
work_keys_str_mv AT ayahmetnedim tetraaquabisorotatokocobaltiidihydrate
AT kosedursunali tetraaquabisorotatokocobaltiidihydrate
AT tercanbarıs tetraaquabisorotatokocobaltiidihydrate
AT yukselfatma tetraaquabisorotatokocobaltiidihydrate
AT hokelektuncer tetraaquabisorotatokocobaltiidihydrate

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