Bis[μ-2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato][2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato]dimanganese(II) perchlorate methanol solvate

In the title complex, [Mn(2)(C(15)H(13)N(2)O(3))(3)]ClO(4)·CH(3)OH, the two Mn(II) ions are bridged by two phenolate O atoms from two ligands, forming an Mn(2)O(2) quadrangle. Each Mn(II) ion has a distorted octa­hedral coordination geometry. One Mn(II) ion is coordinated by two N atoms and four O a...

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Detalles Bibliográficos
Autores principales: Yu, Gui-Miao, Li, Yun-Hui, Zou, Li-Fei, Zhu, Jian-Wei, Liu, Xiao-Qiu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979386/
https://www.ncbi.nlm.nih.gov/pubmed/21579331
http://dx.doi.org/10.1107/S1600536810018040
Descripción
Sumario:In the title complex, [Mn(2)(C(15)H(13)N(2)O(3))(3)]ClO(4)·CH(3)OH, the two Mn(II) ions are bridged by two phenolate O atoms from two ligands, forming an Mn(2)O(2) quadrangle. Each Mn(II) ion has a distorted octa­hedral coordination geometry. One Mn(II) ion is coordinated by two N atoms and four O atoms from two ligands, and the other is coordinated by one N atom and five O atoms from three ligands. A dimer is formed by inter­molecular N—H⋯O hydrogen bonds. The dimers, perchlorate anions and methanol solvent mol­ecules are further connected into a chain along [[Image: see text]01] through N—H⋯O and O—H⋯O hydrogen bonds.

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