Bis[μ-2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato][2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato]dimanganese(II) perchlorate methanol solvate

In the title complex, [Mn(2)(C(15)H(13)N(2)O(3))(3)]ClO(4)·CH(3)OH, the two Mn(II) ions are bridged by two phenolate O atoms from two ligands, forming an Mn(2)O(2) quadrangle. Each Mn(II) ion has a distorted octa­hedral coordination geometry. One Mn(II) ion is coordinated by two N atoms and four O a...

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Autores principales: Yu, Gui-Miao, Li, Yun-Hui, Zou, Li-Fei, Zhu, Jian-Wei, Liu, Xiao-Qiu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979386/
https://www.ncbi.nlm.nih.gov/pubmed/21579331
http://dx.doi.org/10.1107/S1600536810018040
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author Yu, Gui-Miao
Li, Yun-Hui
Zou, Li-Fei
Zhu, Jian-Wei
Liu, Xiao-Qiu
author_facet Yu, Gui-Miao
Li, Yun-Hui
Zou, Li-Fei
Zhu, Jian-Wei
Liu, Xiao-Qiu
author_sort Yu, Gui-Miao
collection PubMed
description In the title complex, [Mn(2)(C(15)H(13)N(2)O(3))(3)]ClO(4)·CH(3)OH, the two Mn(II) ions are bridged by two phenolate O atoms from two ligands, forming an Mn(2)O(2) quadrangle. Each Mn(II) ion has a distorted octa­hedral coordination geometry. One Mn(II) ion is coordinated by two N atoms and four O atoms from two ligands, and the other is coordinated by one N atom and five O atoms from three ligands. A dimer is formed by inter­molecular N—H⋯O hydrogen bonds. The dimers, perchlorate anions and methanol solvent mol­ecules are further connected into a chain along [[Image: see text]01] through N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-29793862010-12-30 Bis[μ-2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato][2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato]dimanganese(II) perchlorate methanol solvate Yu, Gui-Miao Li, Yun-Hui Zou, Li-Fei Zhu, Jian-Wei Liu, Xiao-Qiu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(2)(C(15)H(13)N(2)O(3))(3)]ClO(4)·CH(3)OH, the two Mn(II) ions are bridged by two phenolate O atoms from two ligands, forming an Mn(2)O(2) quadrangle. Each Mn(II) ion has a distorted octa­hedral coordination geometry. One Mn(II) ion is coordinated by two N atoms and four O atoms from two ligands, and the other is coordinated by one N atom and five O atoms from three ligands. A dimer is formed by inter­molecular N—H⋯O hydrogen bonds. The dimers, perchlorate anions and methanol solvent mol­ecules are further connected into a chain along [[Image: see text]01] through N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979386/ /pubmed/21579331 http://dx.doi.org/10.1107/S1600536810018040 Text en © Yu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Gui-Miao
Li, Yun-Hui
Zou, Li-Fei
Zhu, Jian-Wei
Liu, Xiao-Qiu
Bis[μ-2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato][2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato]dimanganese(II) perchlorate methanol solvate
title Bis[μ-2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato][2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato]dimanganese(II) perchlorate methanol solvate
title_full Bis[μ-2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato][2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato]dimanganese(II) perchlorate methanol solvate
title_fullStr Bis[μ-2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato][2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato]dimanganese(II) perchlorate methanol solvate
title_full_unstemmed Bis[μ-2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato][2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato]dimanganese(II) perchlorate methanol solvate
title_short Bis[μ-2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato][2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato]dimanganese(II) perchlorate methanol solvate
title_sort bis[μ-2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato][2-(2-benzoyl­hydrazinylidenemeth­yl)-6-methoxy­phenolato]dimanganese(ii) perchlorate methanol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979386/
https://www.ncbi.nlm.nih.gov/pubmed/21579331
http://dx.doi.org/10.1107/S1600536810018040
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