[(Z)-Ethyl N-isopropyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)

The Au(I) atom in the title compound, [Au(C(6)H(12)NOS)(C(18)H(33)P)], is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S—Au—P angle = 173.44 (5)°], with the distortion due in part to a close intra­molecular Au⋯O contact [3.023 (4) Å]. The N-bound isopropyl gr...

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Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979388/
https://www.ncbi.nlm.nih.gov/pubmed/21579274
http://dx.doi.org/10.1107/S1600536810015801
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author Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_facet Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_sort Tadbuppa, Primjira P.
collection PubMed
description The Au(I) atom in the title compound, [Au(C(6)H(12)NOS)(C(18)H(33)P)], is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S—Au—P angle = 173.44 (5)°], with the distortion due in part to a close intra­molecular Au⋯O contact [3.023 (4) Å]. The N-bound isopropyl group is disordered over two orientations in a 0.618 (15):0.382 (15) ratio.
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spelling pubmed-29793882010-12-30 [(Z)-Ethyl N-isopropyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I) Tadbuppa, Primjira P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Au(I) atom in the title compound, [Au(C(6)H(12)NOS)(C(18)H(33)P)], is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S—Au—P angle = 173.44 (5)°], with the distortion due in part to a close intra­molecular Au⋯O contact [3.023 (4) Å]. The N-bound isopropyl group is disordered over two orientations in a 0.618 (15):0.382 (15) ratio. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979388/ /pubmed/21579274 http://dx.doi.org/10.1107/S1600536810015801 Text en © Tadbuppa and Tiekink 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tadbuppa, Primjira P.
Tiekink, Edward R. T.
[(Z)-Ethyl N-isopropyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title [(Z)-Ethyl N-isopropyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_full [(Z)-Ethyl N-isopropyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_fullStr [(Z)-Ethyl N-isopropyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_full_unstemmed [(Z)-Ethyl N-isopropyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_short [(Z)-Ethyl N-isopropyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_sort [(z)-ethyl n-isopropyl­thio­carbamato-κs](tricyclo­hexyl­phosphine-κp)gold(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979388/
https://www.ncbi.nlm.nih.gov/pubmed/21579274
http://dx.doi.org/10.1107/S1600536810015801
work_keys_str_mv AT tadbuppaprimjirap zethylnisopropylthiocarbamatokstricyclohexylphosphinekpgoldi
AT tiekinkedwardrt zethylnisopropylthiocarbamatokstricyclohexylphosphinekpgoldi

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