Dimethyl 2-(2-quinolylmeth­yl)malonate

In the title compound, C(15)H(15)NO(4), the quinoline ring system and one of the malonate side chains are essentially coplanar (r.m.s. deviation = 0.0297 Å). The two malonate C—C(=O)—O—CH(3) side chains are oriented at right angles [89.68 (8)°] with respect to each other. The crystal packing is stab...

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Autores principales: Liu, Shou-Xin, Zhang, Zhao-Hui, Yang, Yu-Feng, Zhen, Xiao-Li, Han, Jian-Rong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979390/
https://www.ncbi.nlm.nih.gov/pubmed/21579464
http://dx.doi.org/10.1107/S1600536810013930
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author Liu, Shou-Xin
Zhang, Zhao-Hui
Yang, Yu-Feng
Zhen, Xiao-Li
Han, Jian-Rong
author_facet Liu, Shou-Xin
Zhang, Zhao-Hui
Yang, Yu-Feng
Zhen, Xiao-Li
Han, Jian-Rong
author_sort Liu, Shou-Xin
collection PubMed
description In the title compound, C(15)H(15)NO(4), the quinoline ring system and one of the malonate side chains are essentially coplanar (r.m.s. deviation = 0.0297 Å). The two malonate C—C(=O)—O—CH(3) side chains are oriented at right angles [89.68 (8)°] with respect to each other. The crystal packing is stabilized by weak non-classical inter­molecular C—H⋯O hydrogen bonds, which link the mol­ecules into dimers about inversion centers.
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spelling pubmed-29793902010-12-30 Dimethyl 2-(2-quinolylmeth­yl)malonate Liu, Shou-Xin Zhang, Zhao-Hui Yang, Yu-Feng Zhen, Xiao-Li Han, Jian-Rong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(15)NO(4), the quinoline ring system and one of the malonate side chains are essentially coplanar (r.m.s. deviation = 0.0297 Å). The two malonate C—C(=O)—O—CH(3) side chains are oriented at right angles [89.68 (8)°] with respect to each other. The crystal packing is stabilized by weak non-classical inter­molecular C—H⋯O hydrogen bonds, which link the mol­ecules into dimers about inversion centers. International Union of Crystallography 2010-05-19 /pmc/articles/PMC2979390/ /pubmed/21579464 http://dx.doi.org/10.1107/S1600536810013930 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Shou-Xin
Zhang, Zhao-Hui
Yang, Yu-Feng
Zhen, Xiao-Li
Han, Jian-Rong
Dimethyl 2-(2-quinolylmeth­yl)malonate
title Dimethyl 2-(2-quinolylmeth­yl)malonate
title_full Dimethyl 2-(2-quinolylmeth­yl)malonate
title_fullStr Dimethyl 2-(2-quinolylmeth­yl)malonate
title_full_unstemmed Dimethyl 2-(2-quinolylmeth­yl)malonate
title_short Dimethyl 2-(2-quinolylmeth­yl)malonate
title_sort dimethyl 2-(2-quinolylmeth­yl)malonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979390/
https://www.ncbi.nlm.nih.gov/pubmed/21579464
http://dx.doi.org/10.1107/S1600536810013930
work_keys_str_mv AT liushouxin dimethyl22quinolylmethylmalonate
AT zhangzhaohui dimethyl22quinolylmethylmalonate
AT yangyufeng dimethyl22quinolylmethylmalonate
AT zhenxiaoli dimethyl22quinolylmethylmalonate
AT hanjianrong dimethyl22quinolylmethylmalonate

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