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3,3′-Dimethyl-1,1′-(butane-1,4-diyl)diimidazolium bis(tetrafluoroborate)
The title compound, C(12)H(20)N(4) (2+)·2BF(4) (−), was prepared by the anion exchange of a dibromide ionic liquid with sodium tetrafluoroborate. The asymmetric unit contains one half of the imidazolium cation, which lies about an inversion centre at the mid-point of the central C—C bond of the li...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979393/ https://www.ncbi.nlm.nih.gov/pubmed/21579368 http://dx.doi.org/10.1107/S160053681001593X |
Sumario: | The title compound, C(12)H(20)N(4) (2+)·2BF(4) (−), was prepared by the anion exchange of a dibromide ionic liquid with sodium tetrafluoroborate. The asymmetric unit contains one half of the imidazolium cation, which lies about an inversion centre at the mid-point of the central C—C bond of the linking butyl chain. The two planar imidazole rings (r.m.s. deviation = 0.0013 Å) are strictly parallel and separated by 2.625 (7) Å [vertical distance between the centroids of two imidazole rings], giving the molecule a stepped appearance. In the crystal structure, intermolecular C—H⋯F hydrogen bonds link the cations and anions, generating a three-dimensional network. |
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