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3,3′-Dimethyl-1,1′-(butane-1,4-diyl)diimidazolium bis(tetrafluoroborate)
The title compound, C(12)H(20)N(4) (2+)·2BF(4) (−), was prepared by the anion exchange of a dibromide ionic liquid with sodium tetrafluoroborate. The asymmetric unit contains one half of the imidazolium cation, which lies about an inversion centre at the mid-point of the central C—C bond of the li...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979393/ https://www.ncbi.nlm.nih.gov/pubmed/21579368 http://dx.doi.org/10.1107/S160053681001593X |
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author | Geng, Hao Zhuang, Ling-hua Zhang, Jian Wang, Guo-wei Yuan, Ai-lin |
author_facet | Geng, Hao Zhuang, Ling-hua Zhang, Jian Wang, Guo-wei Yuan, Ai-lin |
author_sort | Geng, Hao |
collection | PubMed |
description | The title compound, C(12)H(20)N(4) (2+)·2BF(4) (−), was prepared by the anion exchange of a dibromide ionic liquid with sodium tetrafluoroborate. The asymmetric unit contains one half of the imidazolium cation, which lies about an inversion centre at the mid-point of the central C—C bond of the linking butyl chain. The two planar imidazole rings (r.m.s. deviation = 0.0013 Å) are strictly parallel and separated by 2.625 (7) Å [vertical distance between the centroids of two imidazole rings], giving the molecule a stepped appearance. In the crystal structure, intermolecular C—H⋯F hydrogen bonds link the cations and anions, generating a three-dimensional network. |
format | Text |
id | pubmed-2979393 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29793932010-12-30 3,3′-Dimethyl-1,1′-(butane-1,4-diyl)diimidazolium bis(tetrafluoroborate) Geng, Hao Zhuang, Ling-hua Zhang, Jian Wang, Guo-wei Yuan, Ai-lin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(20)N(4) (2+)·2BF(4) (−), was prepared by the anion exchange of a dibromide ionic liquid with sodium tetrafluoroborate. The asymmetric unit contains one half of the imidazolium cation, which lies about an inversion centre at the mid-point of the central C—C bond of the linking butyl chain. The two planar imidazole rings (r.m.s. deviation = 0.0013 Å) are strictly parallel and separated by 2.625 (7) Å [vertical distance between the centroids of two imidazole rings], giving the molecule a stepped appearance. In the crystal structure, intermolecular C—H⋯F hydrogen bonds link the cations and anions, generating a three-dimensional network. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979393/ /pubmed/21579368 http://dx.doi.org/10.1107/S160053681001593X Text en © Geng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Geng, Hao Zhuang, Ling-hua Zhang, Jian Wang, Guo-wei Yuan, Ai-lin 3,3′-Dimethyl-1,1′-(butane-1,4-diyl)diimidazolium bis(tetrafluoroborate) |
title | 3,3′-Dimethyl-1,1′-(butane-1,4-diyl)diimidazolium bis(tetrafluoroborate) |
title_full | 3,3′-Dimethyl-1,1′-(butane-1,4-diyl)diimidazolium bis(tetrafluoroborate) |
title_fullStr | 3,3′-Dimethyl-1,1′-(butane-1,4-diyl)diimidazolium bis(tetrafluoroborate) |
title_full_unstemmed | 3,3′-Dimethyl-1,1′-(butane-1,4-diyl)diimidazolium bis(tetrafluoroborate) |
title_short | 3,3′-Dimethyl-1,1′-(butane-1,4-diyl)diimidazolium bis(tetrafluoroborate) |
title_sort | 3,3′-dimethyl-1,1′-(butane-1,4-diyl)diimidazolium bis(tetrafluoroborate) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979393/ https://www.ncbi.nlm.nih.gov/pubmed/21579368 http://dx.doi.org/10.1107/S160053681001593X |
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