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3,3′-Dimethyl-1,1′-(butane-1,4-di­yl)diimidazolium bis­(tetra­fluoro­borate)

The title compound, C(12)H(20)N(4) (2+)·2BF(4) (−), was prepared by the anion exchange of a dibromide ionic liquid with sodium tetra­fluoro­borate. The asymmetric unit contains one half of the imidazolium cation, which lies about an inversion centre at the mid-point of the central C—C bond of the li...

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Detalles Bibliográficos
Autores principales: Geng, Hao, Zhuang, Ling-hua, Zhang, Jian, Wang, Guo-wei, Yuan, Ai-lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979393/
https://www.ncbi.nlm.nih.gov/pubmed/21579368
http://dx.doi.org/10.1107/S160053681001593X
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author Geng, Hao
Zhuang, Ling-hua
Zhang, Jian
Wang, Guo-wei
Yuan, Ai-lin
author_facet Geng, Hao
Zhuang, Ling-hua
Zhang, Jian
Wang, Guo-wei
Yuan, Ai-lin
author_sort Geng, Hao
collection PubMed
description The title compound, C(12)H(20)N(4) (2+)·2BF(4) (−), was prepared by the anion exchange of a dibromide ionic liquid with sodium tetra­fluoro­borate. The asymmetric unit contains one half of the imidazolium cation, which lies about an inversion centre at the mid-point of the central C—C bond of the linking butyl chain. The two planar imidazole rings (r.m.s. deviation = 0.0013 Å) are strictly parallel and separated by 2.625 (7) Å [vertical distance between the centroids of two imidazole rings], giving the mol­ecule a stepped appearance. In the crystal structure, inter­molecular C—H⋯F hydrogen bonds link the cations and anions, generating a three-dimensional network.
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spelling pubmed-29793932010-12-30 3,3′-Dimethyl-1,1′-(butane-1,4-di­yl)diimidazolium bis­(tetra­fluoro­borate) Geng, Hao Zhuang, Ling-hua Zhang, Jian Wang, Guo-wei Yuan, Ai-lin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(20)N(4) (2+)·2BF(4) (−), was prepared by the anion exchange of a dibromide ionic liquid with sodium tetra­fluoro­borate. The asymmetric unit contains one half of the imidazolium cation, which lies about an inversion centre at the mid-point of the central C—C bond of the linking butyl chain. The two planar imidazole rings (r.m.s. deviation = 0.0013 Å) are strictly parallel and separated by 2.625 (7) Å [vertical distance between the centroids of two imidazole rings], giving the mol­ecule a stepped appearance. In the crystal structure, inter­molecular C—H⋯F hydrogen bonds link the cations and anions, generating a three-dimensional network. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979393/ /pubmed/21579368 http://dx.doi.org/10.1107/S160053681001593X Text en © Geng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Geng, Hao
Zhuang, Ling-hua
Zhang, Jian
Wang, Guo-wei
Yuan, Ai-lin
3,3′-Dimethyl-1,1′-(butane-1,4-di­yl)diimidazolium bis­(tetra­fluoro­borate)
title 3,3′-Dimethyl-1,1′-(butane-1,4-di­yl)diimidazolium bis­(tetra­fluoro­borate)
title_full 3,3′-Dimethyl-1,1′-(butane-1,4-di­yl)diimidazolium bis­(tetra­fluoro­borate)
title_fullStr 3,3′-Dimethyl-1,1′-(butane-1,4-di­yl)diimidazolium bis­(tetra­fluoro­borate)
title_full_unstemmed 3,3′-Dimethyl-1,1′-(butane-1,4-di­yl)diimidazolium bis­(tetra­fluoro­borate)
title_short 3,3′-Dimethyl-1,1′-(butane-1,4-di­yl)diimidazolium bis­(tetra­fluoro­borate)
title_sort 3,3′-dimethyl-1,1′-(butane-1,4-di­yl)diimidazolium bis­(tetra­fluoro­borate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979393/
https://www.ncbi.nlm.nih.gov/pubmed/21579368
http://dx.doi.org/10.1107/S160053681001593X
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