5-Methyl-2,4-bis­(methyl­sulfan­yl)tricyclo­[6.2.1.0(2,7)]undeca-4,9-diene-3,6-dione

The structure analysis of the title compound, C(14)H(16)O(2)S(2), shows the SMe and H atoms of the bond linking the six-membered rings to be syn and also to be syn to the bridgehead –CH(2)– group. Each of the five-membered rings adopts an envelope conformation at the bridgehead –CH(2)– group. The di...

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Autores principales: von Richthofen, Andreas A., Cardoso Filho, José E. P., Marzorati, Liliana, Zukerman-Schpector, Julio, Tiekink, Edward R. T., Di Vitta, Claudio
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979396/
https://www.ncbi.nlm.nih.gov/pubmed/21579362
http://dx.doi.org/10.1107/S1600536810015710
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author von Richthofen, Andreas A.
Cardoso Filho, José E. P.
Marzorati, Liliana
Zukerman-Schpector, Julio
Tiekink, Edward R. T.
Di Vitta, Claudio
author_facet von Richthofen, Andreas A.
Cardoso Filho, José E. P.
Marzorati, Liliana
Zukerman-Schpector, Julio
Tiekink, Edward R. T.
Di Vitta, Claudio
author_sort von Richthofen, Andreas A.
collection PubMed
description The structure analysis of the title compound, C(14)H(16)O(2)S(2), shows the SMe and H atoms of the bond linking the six-membered rings to be syn and also to be syn to the bridgehead –CH(2)– group. Each of the five-membered rings adopts an envelope conformation at the bridgehead –CH(2)– group. The dione-substituted ring adopts a folded conformation about the 1,4-C⋯C vector, with the ketone groups lying to one side. The cyclo­hexene ring adopts a boat conformation.
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spelling pubmed-29793962010-12-30 5-Methyl-2,4-bis­(methyl­sulfan­yl)tricyclo­[6.2.1.0(2,7)]undeca-4,9-diene-3,6-dione von Richthofen, Andreas A. Cardoso Filho, José E. P. Marzorati, Liliana Zukerman-Schpector, Julio Tiekink, Edward R. T. Di Vitta, Claudio Acta Crystallogr Sect E Struct Rep Online Organic Papers The structure analysis of the title compound, C(14)H(16)O(2)S(2), shows the SMe and H atoms of the bond linking the six-membered rings to be syn and also to be syn to the bridgehead –CH(2)– group. Each of the five-membered rings adopts an envelope conformation at the bridgehead –CH(2)– group. The dione-substituted ring adopts a folded conformation about the 1,4-C⋯C vector, with the ketone groups lying to one side. The cyclo­hexene ring adopts a boat conformation. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979396/ /pubmed/21579362 http://dx.doi.org/10.1107/S1600536810015710 Text en © Richthofen et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
von Richthofen, Andreas A.
Cardoso Filho, José E. P.
Marzorati, Liliana
Zukerman-Schpector, Julio
Tiekink, Edward R. T.
Di Vitta, Claudio
5-Methyl-2,4-bis­(methyl­sulfan­yl)tricyclo­[6.2.1.0(2,7)]undeca-4,9-diene-3,6-dione
title 5-Methyl-2,4-bis­(methyl­sulfan­yl)tricyclo­[6.2.1.0(2,7)]undeca-4,9-diene-3,6-dione
title_full 5-Methyl-2,4-bis­(methyl­sulfan­yl)tricyclo­[6.2.1.0(2,7)]undeca-4,9-diene-3,6-dione
title_fullStr 5-Methyl-2,4-bis­(methyl­sulfan­yl)tricyclo­[6.2.1.0(2,7)]undeca-4,9-diene-3,6-dione
title_full_unstemmed 5-Methyl-2,4-bis­(methyl­sulfan­yl)tricyclo­[6.2.1.0(2,7)]undeca-4,9-diene-3,6-dione
title_short 5-Methyl-2,4-bis­(methyl­sulfan­yl)tricyclo­[6.2.1.0(2,7)]undeca-4,9-diene-3,6-dione
title_sort 5-methyl-2,4-bis­(methyl­sulfan­yl)tricyclo­[6.2.1.0(2,7)]undeca-4,9-diene-3,6-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979396/
https://www.ncbi.nlm.nih.gov/pubmed/21579362
http://dx.doi.org/10.1107/S1600536810015710
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