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catena-Poly[[bis(nitrato-κ(2) O,O′)cobalt(II)]-μ-4,4′-bis(pyrazol-1-ylmethyl)biphenyl-κ(2) N (2):N (2′)]
In the title compound, [Co(NO(3))(2)(C(20)H(18)N(4))](n), the Co(II) atom lies on a crystallographic twofold axis and the coordination geometry can be considered as a slightly distorted tetrahedron defined by two O atoms from two nitrate groups and two N atoms from two ligand molecules. A distorte...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979397/ https://www.ncbi.nlm.nih.gov/pubmed/21579349 http://dx.doi.org/10.1107/S160053681001977X |
Sumario: | In the title compound, [Co(NO(3))(2)(C(20)H(18)N(4))](n), the Co(II) atom lies on a crystallographic twofold axis and the coordination geometry can be considered as a slightly distorted tetrahedron defined by two O atoms from two nitrate groups and two N atoms from two ligand molecules. A distorted octahedron may be assumed when two of the symmetry-related nitrate O atoms with Co—O distances of 2.3449 (19) Å are added to the coordination environment. Another twofold axis, passing through the middle of the biphenyl bonds, is observed in the crystal structure. A chain is built up by the ligands linking the Co(II) ions along [101]. |
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