Cargando…

catena-Poly[[bis­(nitrato-κ(2) O,O′)cobalt(II)]-μ-4,4′-bis­(pyrazol-1-ylmeth­yl)biphenyl-κ(2) N (2):N (2′)]

In the title compound, [Co(NO(3))(2)(C(20)H(18)N(4))](n), the Co(II) atom lies on a crystallographic twofold axis and the coordination geometry can be considered as a slightly distorted tetra­hedron defined by two O atoms from two nitrate groups and two N atoms from two ligand mol­ecules. A distorte...

Descripción completa

Detalles Bibliográficos
Autores principales: Gao, Jin-Sheng, Wang, Xue, Ding, Zhi-Yong, Hou, Guang-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979397/
https://www.ncbi.nlm.nih.gov/pubmed/21579349
http://dx.doi.org/10.1107/S160053681001977X
Descripción
Sumario:In the title compound, [Co(NO(3))(2)(C(20)H(18)N(4))](n), the Co(II) atom lies on a crystallographic twofold axis and the coordination geometry can be considered as a slightly distorted tetra­hedron defined by two O atoms from two nitrate groups and two N atoms from two ligand mol­ecules. A distorted octa­hedron may be assumed when two of the symmetry-related nitrate O atoms with Co—O distances of 2.3449 (19) Å are added to the coordination environment. Another twofold axis, passing through the middle of the biphenyl bonds, is observed in the crystal structure. A chain is built up by the ligands linking the Co(II) ions along [101].