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catena-Poly[[bis(nitrato-κ(2) O,O′)cobalt(II)]-μ-4,4′-bis(pyrazol-1-ylmethyl)biphenyl-κ(2) N (2):N (2′)]
In the title compound, [Co(NO(3))(2)(C(20)H(18)N(4))](n), the Co(II) atom lies on a crystallographic twofold axis and the coordination geometry can be considered as a slightly distorted tetrahedron defined by two O atoms from two nitrate groups and two N atoms from two ligand molecules. A distorte...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979397/ https://www.ncbi.nlm.nih.gov/pubmed/21579349 http://dx.doi.org/10.1107/S160053681001977X |
| _version_ | 1782191402900258816 |
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| author | Gao, Jin-Sheng Wang, Xue Ding, Zhi-Yong Hou, Guang-Feng |
| author_facet | Gao, Jin-Sheng Wang, Xue Ding, Zhi-Yong Hou, Guang-Feng |
| author_sort | Gao, Jin-Sheng |
| collection | PubMed |
| description | In the title compound, [Co(NO(3))(2)(C(20)H(18)N(4))](n), the Co(II) atom lies on a crystallographic twofold axis and the coordination geometry can be considered as a slightly distorted tetrahedron defined by two O atoms from two nitrate groups and two N atoms from two ligand molecules. A distorted octahedron may be assumed when two of the symmetry-related nitrate O atoms with Co—O distances of 2.3449 (19) Å are added to the coordination environment. Another twofold axis, passing through the middle of the biphenyl bonds, is observed in the crystal structure. A chain is built up by the ligands linking the Co(II) ions along [101]. |
| format | Text |
| id | pubmed-2979397 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29793972010-12-30 catena-Poly[[bis(nitrato-κ(2) O,O′)cobalt(II)]-μ-4,4′-bis(pyrazol-1-ylmethyl)biphenyl-κ(2) N (2):N (2′)] Gao, Jin-Sheng Wang, Xue Ding, Zhi-Yong Hou, Guang-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(NO(3))(2)(C(20)H(18)N(4))](n), the Co(II) atom lies on a crystallographic twofold axis and the coordination geometry can be considered as a slightly distorted tetrahedron defined by two O atoms from two nitrate groups and two N atoms from two ligand molecules. A distorted octahedron may be assumed when two of the symmetry-related nitrate O atoms with Co—O distances of 2.3449 (19) Å are added to the coordination environment. Another twofold axis, passing through the middle of the biphenyl bonds, is observed in the crystal structure. A chain is built up by the ligands linking the Co(II) ions along [101]. International Union of Crystallography 2010-05-29 /pmc/articles/PMC2979397/ /pubmed/21579349 http://dx.doi.org/10.1107/S160053681001977X Text en © Gao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Gao, Jin-Sheng Wang, Xue Ding, Zhi-Yong Hou, Guang-Feng catena-Poly[[bis(nitrato-κ(2) O,O′)cobalt(II)]-μ-4,4′-bis(pyrazol-1-ylmethyl)biphenyl-κ(2) N (2):N (2′)] |
| title |
catena-Poly[[bis(nitrato-κ(2)
O,O′)cobalt(II)]-μ-4,4′-bis(pyrazol-1-ylmethyl)biphenyl-κ(2)
N
(2):N
(2′)] |
| title_full |
catena-Poly[[bis(nitrato-κ(2)
O,O′)cobalt(II)]-μ-4,4′-bis(pyrazol-1-ylmethyl)biphenyl-κ(2)
N
(2):N
(2′)] |
| title_fullStr |
catena-Poly[[bis(nitrato-κ(2)
O,O′)cobalt(II)]-μ-4,4′-bis(pyrazol-1-ylmethyl)biphenyl-κ(2)
N
(2):N
(2′)] |
| title_full_unstemmed |
catena-Poly[[bis(nitrato-κ(2)
O,O′)cobalt(II)]-μ-4,4′-bis(pyrazol-1-ylmethyl)biphenyl-κ(2)
N
(2):N
(2′)] |
| title_short |
catena-Poly[[bis(nitrato-κ(2)
O,O′)cobalt(II)]-μ-4,4′-bis(pyrazol-1-ylmethyl)biphenyl-κ(2)
N
(2):N
(2′)] |
| title_sort | catena-poly[[bis(nitrato-κ(2)
o,o′)cobalt(ii)]-μ-4,4′-bis(pyrazol-1-ylmethyl)biphenyl-κ(2)
n
(2):n
(2′)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979397/ https://www.ncbi.nlm.nih.gov/pubmed/21579349 http://dx.doi.org/10.1107/S160053681001977X |
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