N-Benzyl-2-(2-bromo­phen­yl)-2-(2-nitro­phen­oxy)acetamide

The title compound, C(21)H(17)BrN(2)O(4), a 2-phen­oxy-2-phenyl­acetamide derivative, exhibits a stereogenic center but crystallizes as a racemate as indicated by the centrosymmetric space group. In the mol­ecular structure, the nitro-substituted benzene ring is coplanar [dihedral angle = 12.9 (1)°]...

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Detalles Bibliográficos
Autores principales: Li, Huo Ming, Wu, Jin-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979402/
https://www.ncbi.nlm.nih.gov/pubmed/21579375
http://dx.doi.org/10.1107/S1600536810014996
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author Li, Huo Ming
Wu, Jin-Long
author_facet Li, Huo Ming
Wu, Jin-Long
author_sort Li, Huo Ming
collection PubMed
description The title compound, C(21)H(17)BrN(2)O(4), a 2-phen­oxy-2-phenyl­acetamide derivative, exhibits a stereogenic center but crystallizes as a racemate as indicated by the centrosymmetric space group. In the mol­ecular structure, the nitro-substituted benzene ring is coplanar [dihedral angle = 12.9 (1)°] with the plane formed by H—N—C(=O)—C=O due to intra­molecular N—H⋯O hydrogen-bond inter­actions.
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spelling pubmed-29794022010-12-30 N-Benzyl-2-(2-bromo­phen­yl)-2-(2-nitro­phen­oxy)acetamide Li, Huo Ming Wu, Jin-Long Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(17)BrN(2)O(4), a 2-phen­oxy-2-phenyl­acetamide derivative, exhibits a stereogenic center but crystallizes as a racemate as indicated by the centrosymmetric space group. In the mol­ecular structure, the nitro-substituted benzene ring is coplanar [dihedral angle = 12.9 (1)°] with the plane formed by H—N—C(=O)—C=O due to intra­molecular N—H⋯O hydrogen-bond inter­actions. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979402/ /pubmed/21579375 http://dx.doi.org/10.1107/S1600536810014996 Text en © Li and Wu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Huo Ming
Wu, Jin-Long
N-Benzyl-2-(2-bromo­phen­yl)-2-(2-nitro­phen­oxy)acetamide
title N-Benzyl-2-(2-bromo­phen­yl)-2-(2-nitro­phen­oxy)acetamide
title_full N-Benzyl-2-(2-bromo­phen­yl)-2-(2-nitro­phen­oxy)acetamide
title_fullStr N-Benzyl-2-(2-bromo­phen­yl)-2-(2-nitro­phen­oxy)acetamide
title_full_unstemmed N-Benzyl-2-(2-bromo­phen­yl)-2-(2-nitro­phen­oxy)acetamide
title_short N-Benzyl-2-(2-bromo­phen­yl)-2-(2-nitro­phen­oxy)acetamide
title_sort n-benzyl-2-(2-bromo­phen­yl)-2-(2-nitro­phen­oxy)acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979402/
https://www.ncbi.nlm.nih.gov/pubmed/21579375
http://dx.doi.org/10.1107/S1600536810014996
work_keys_str_mv AT lihuoming nbenzyl22bromophenyl22nitrophenoxyacetamide
AT wujinlong nbenzyl22bromophenyl22nitrophenoxyacetamide

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