N-[(Morpholin-4-yl)carbonothio­yl]-4-nitro­benzamide

In the title compound, C(12)H(13)N(3)O(4)S, the nitro group is slightly twisted [6.58 (11)°] from the benzene ring plane. The morpholine ring adopts a chair form. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains along [110]. There are also π–π contacts [centroid–c...

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Detalles Bibliográficos
Autores principales: Saeed, Sohail, Mehmood, Rashid, Wong, Wing-Tak, Waris, Ghulam, Manan, Abdul
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979403/
https://www.ncbi.nlm.nih.gov/pubmed/21579507
http://dx.doi.org/10.1107/S1600536810018763
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author Saeed, Sohail
Mehmood, Rashid
Wong, Wing-Tak
Waris, Ghulam
Manan, Abdul
author_facet Saeed, Sohail
Mehmood, Rashid
Wong, Wing-Tak
Waris, Ghulam
Manan, Abdul
author_sort Saeed, Sohail
collection PubMed
description In the title compound, C(12)H(13)N(3)O(4)S, the nitro group is slightly twisted [6.58 (11)°] from the benzene ring plane. The morpholine ring adopts a chair form. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains along [110]. There are also π–π contacts [centroid–centroid distance = 3.8301 (11) Å] and C—H⋯π inter­actions to stack neighbouring benzene rings and link the chains into a three-dimensional network. C—H⋯O and C—H⋯S inter­actions are also observed.
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spelling pubmed-29794032010-12-30 N-[(Morpholin-4-yl)carbonothio­yl]-4-nitro­benzamide Saeed, Sohail Mehmood, Rashid Wong, Wing-Tak Waris, Ghulam Manan, Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(13)N(3)O(4)S, the nitro group is slightly twisted [6.58 (11)°] from the benzene ring plane. The morpholine ring adopts a chair form. In the crystal, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains along [110]. There are also π–π contacts [centroid–centroid distance = 3.8301 (11) Å] and C—H⋯π inter­actions to stack neighbouring benzene rings and link the chains into a three-dimensional network. C—H⋯O and C—H⋯S inter­actions are also observed. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979403/ /pubmed/21579507 http://dx.doi.org/10.1107/S1600536810018763 Text en © Saeed et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saeed, Sohail
Mehmood, Rashid
Wong, Wing-Tak
Waris, Ghulam
Manan, Abdul
N-[(Morpholin-4-yl)carbonothio­yl]-4-nitro­benzamide
title N-[(Morpholin-4-yl)carbonothio­yl]-4-nitro­benzamide
title_full N-[(Morpholin-4-yl)carbonothio­yl]-4-nitro­benzamide
title_fullStr N-[(Morpholin-4-yl)carbonothio­yl]-4-nitro­benzamide
title_full_unstemmed N-[(Morpholin-4-yl)carbonothio­yl]-4-nitro­benzamide
title_short N-[(Morpholin-4-yl)carbonothio­yl]-4-nitro­benzamide
title_sort n-[(morpholin-4-yl)carbonothio­yl]-4-nitro­benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979403/
https://www.ncbi.nlm.nih.gov/pubmed/21579507
http://dx.doi.org/10.1107/S1600536810018763
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