Bis{1,2-bis­[2-(1H-imidazol-1-yl)eth­oxy]ethane-κ(2) N (3),N (3′)}dichloridocadmium(II) monohydrate

The asymmetric unit of the title compound, [CdCl(2)(C(12)H(18)N(4)O(2))(2)]·H(2)O, contains one water mol­ecule and two halves of a [CdCl(2)(BIEE)(2)] complex mol­ecule {BIEE is 1,2-bis­[2-(1H-imidazol-1-yl)eth­oxy]ethane}, with the Cd(II) atoms lying on inversion centres. Each metal atom displays a...

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Detalles Bibliográficos
Autor principal: Liu, Guang-Xiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979405/
https://www.ncbi.nlm.nih.gov/pubmed/21579346
http://dx.doi.org/10.1107/S1600536810019148
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author Liu, Guang-Xiang
author_facet Liu, Guang-Xiang
author_sort Liu, Guang-Xiang
collection PubMed
description The asymmetric unit of the title compound, [CdCl(2)(C(12)H(18)N(4)O(2))(2)]·H(2)O, contains one water mol­ecule and two halves of a [CdCl(2)(BIEE)(2)] complex mol­ecule {BIEE is 1,2-bis­[2-(1H-imidazol-1-yl)eth­oxy]ethane}, with the Cd(II) atoms lying on inversion centres. Each metal atom displays an elongated octa­hedral coordination geometry provided by two trans-arranged chloride anions and four N atoms from two BIEE ligands. Weak O—H⋯Cl hydrogen-bond inter­actions contribute to the stability of the crystal packing.
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spelling pubmed-29794052010-12-30 Bis{1,2-bis­[2-(1H-imidazol-1-yl)eth­oxy]ethane-κ(2) N (3),N (3′)}dichloridocadmium(II) monohydrate Liu, Guang-Xiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [CdCl(2)(C(12)H(18)N(4)O(2))(2)]·H(2)O, contains one water mol­ecule and two halves of a [CdCl(2)(BIEE)(2)] complex mol­ecule {BIEE is 1,2-bis­[2-(1H-imidazol-1-yl)eth­oxy]ethane}, with the Cd(II) atoms lying on inversion centres. Each metal atom displays an elongated octa­hedral coordination geometry provided by two trans-arranged chloride anions and four N atoms from two BIEE ligands. Weak O—H⋯Cl hydrogen-bond inter­actions contribute to the stability of the crystal packing. International Union of Crystallography 2010-05-29 /pmc/articles/PMC2979405/ /pubmed/21579346 http://dx.doi.org/10.1107/S1600536810019148 Text en © Guang-Xiang Liu 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Guang-Xiang
Bis{1,2-bis­[2-(1H-imidazol-1-yl)eth­oxy]ethane-κ(2) N (3),N (3′)}dichloridocadmium(II) monohydrate
title Bis{1,2-bis­[2-(1H-imidazol-1-yl)eth­oxy]ethane-κ(2) N (3),N (3′)}dichloridocadmium(II) monohydrate
title_full Bis{1,2-bis­[2-(1H-imidazol-1-yl)eth­oxy]ethane-κ(2) N (3),N (3′)}dichloridocadmium(II) monohydrate
title_fullStr Bis{1,2-bis­[2-(1H-imidazol-1-yl)eth­oxy]ethane-κ(2) N (3),N (3′)}dichloridocadmium(II) monohydrate
title_full_unstemmed Bis{1,2-bis­[2-(1H-imidazol-1-yl)eth­oxy]ethane-κ(2) N (3),N (3′)}dichloridocadmium(II) monohydrate
title_short Bis{1,2-bis­[2-(1H-imidazol-1-yl)eth­oxy]ethane-κ(2) N (3),N (3′)}dichloridocadmium(II) monohydrate
title_sort bis{1,2-bis­[2-(1h-imidazol-1-yl)eth­oxy]ethane-κ(2) n (3),n (3′)}dichloridocadmium(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979405/
https://www.ncbi.nlm.nih.gov/pubmed/21579346
http://dx.doi.org/10.1107/S1600536810019148
work_keys_str_mv AT liuguangxiang bis12bis21himidazol1ylethoxyethanek2n3n3dichloridocadmiumiimonohydrate

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