Lutetium(III) cyclo­tetra­phosphate

Single crystals of the title compound, tetra­lutetium(III) tris­(cyclo­tetra­phosphate), Lu(4)(P(4)O(12))(3), were obtained by solid-state reaction. The cubic structure is isotypic with its Al(III) and Sc(III) analogues and is built up from four-membered (P(4)O(12))(4−) phosphate ring anions ([Image...

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Autores principales: Mbarek, Aïcha, Fourati, Mohieddine, Zambon, Daniel, Avignant, Daniel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979408/
https://www.ncbi.nlm.nih.gov/pubmed/21579264
http://dx.doi.org/10.1107/S1600536810016363
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author Mbarek, Aïcha
Fourati, Mohieddine
Zambon, Daniel
Avignant, Daniel
author_facet Mbarek, Aïcha
Fourati, Mohieddine
Zambon, Daniel
Avignant, Daniel
author_sort Mbarek, Aïcha
collection PubMed
description Single crystals of the title compound, tetra­lutetium(III) tris­(cyclo­tetra­phosphate), Lu(4)(P(4)O(12))(3), were obtained by solid-state reaction. The cubic structure is isotypic with its Al(III) and Sc(III) analogues and is built up from four-membered (P(4)O(12))(4−) phosphate ring anions ([Image: see text] symmetry), isolated from each other and further linked through isolated LuO(6) octa­hedra (.3. symmetry) via corner sharing. Each LuO(6) octa­hedron is linked to six (P(4)O(12))(4−) rings, while each (P(4)O(12))(4−) ring is linked to eight LuO(6) octa­hedra.
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spelling pubmed-29794082010-12-30 Lutetium(III) cyclo­tetra­phosphate Mbarek, Aïcha Fourati, Mohieddine Zambon, Daniel Avignant, Daniel Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of the title compound, tetra­lutetium(III) tris­(cyclo­tetra­phosphate), Lu(4)(P(4)O(12))(3), were obtained by solid-state reaction. The cubic structure is isotypic with its Al(III) and Sc(III) analogues and is built up from four-membered (P(4)O(12))(4−) phosphate ring anions ([Image: see text] symmetry), isolated from each other and further linked through isolated LuO(6) octa­hedra (.3. symmetry) via corner sharing. Each LuO(6) octa­hedron is linked to six (P(4)O(12))(4−) rings, while each (P(4)O(12))(4−) ring is linked to eight LuO(6) octa­hedra. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979408/ /pubmed/21579264 http://dx.doi.org/10.1107/S1600536810016363 Text en © Mbarek et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Mbarek, Aïcha
Fourati, Mohieddine
Zambon, Daniel
Avignant, Daniel
Lutetium(III) cyclo­tetra­phosphate
title Lutetium(III) cyclo­tetra­phosphate
title_full Lutetium(III) cyclo­tetra­phosphate
title_fullStr Lutetium(III) cyclo­tetra­phosphate
title_full_unstemmed Lutetium(III) cyclo­tetra­phosphate
title_short Lutetium(III) cyclo­tetra­phosphate
title_sort lutetium(iii) cyclo­tetra­phosphate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979408/
https://www.ncbi.nlm.nih.gov/pubmed/21579264
http://dx.doi.org/10.1107/S1600536810016363
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AT fouratimohieddine lutetiumiiicyclotetraphosphate
AT zambondaniel lutetiumiiicyclotetraphosphate
AT avignantdaniel lutetiumiiicyclotetraphosphate

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