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Poly[(μ(6)-2-methyl-3,5-dinitro­benzoato)potassium]

In the structure of the title coordination polymer, [K(C(8)H(5)N(2)O(6))](n), each ligand bridges six K(+) cations. The carboxyl­ate group coordinates both bidentately to one K(+) ion and monodentately to two K(+) ions, while one nitro group coordinates bidentately to a fourth K(+) ion. The last two...

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Detalles Bibliográficos
Autores principales: Danish, Muhammad, Saleem, Iram, Ahmad, Nazir, Starosta, Wojciech, Leciejewicz, Janusz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979411/
https://www.ncbi.nlm.nih.gov/pubmed/21579275
http://dx.doi.org/10.1107/S1600536810015400
Descripción
Sumario:In the structure of the title coordination polymer, [K(C(8)H(5)N(2)O(6))](n), each ligand bridges six K(+) cations. The carboxyl­ate group coordinates both bidentately to one K(+) ion and monodentately to two K(+) ions, while one nitro group coordinates bidentately to a fourth K(+) ion. The last two K(+) ions are coordinated by the remaining nitro group, one in a bidentate fashion, the other monodentately through one O atom. This bridging mode results in a three-dimensional network. The coordination geometry of the K(+) ion is represented by an irregular KO(9) polyhedron. Very weak C—H⋯O inter­actions are observed in the crystal structure.