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Poly[(μ(6)-2-methyl-3,5-dinitro­benzoato)potassium]

In the structure of the title coordination polymer, [K(C(8)H(5)N(2)O(6))](n), each ligand bridges six K(+) cations. The carboxyl­ate group coordinates both bidentately to one K(+) ion and monodentately to two K(+) ions, while one nitro group coordinates bidentately to a fourth K(+) ion. The last two...

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Detalles Bibliográficos
Autores principales: Danish, Muhammad, Saleem, Iram, Ahmad, Nazir, Starosta, Wojciech, Leciejewicz, Janusz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979411/
https://www.ncbi.nlm.nih.gov/pubmed/21579275
http://dx.doi.org/10.1107/S1600536810015400
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author Danish, Muhammad
Saleem, Iram
Ahmad, Nazir
Starosta, Wojciech
Leciejewicz, Janusz
author_facet Danish, Muhammad
Saleem, Iram
Ahmad, Nazir
Starosta, Wojciech
Leciejewicz, Janusz
author_sort Danish, Muhammad
collection PubMed
description In the structure of the title coordination polymer, [K(C(8)H(5)N(2)O(6))](n), each ligand bridges six K(+) cations. The carboxyl­ate group coordinates both bidentately to one K(+) ion and monodentately to two K(+) ions, while one nitro group coordinates bidentately to a fourth K(+) ion. The last two K(+) ions are coordinated by the remaining nitro group, one in a bidentate fashion, the other monodentately through one O atom. This bridging mode results in a three-dimensional network. The coordination geometry of the K(+) ion is represented by an irregular KO(9) polyhedron. Very weak C—H⋯O inter­actions are observed in the crystal structure.
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spelling pubmed-29794112010-12-30 Poly[(μ(6)-2-methyl-3,5-dinitro­benzoato)potassium] Danish, Muhammad Saleem, Iram Ahmad, Nazir Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title coordination polymer, [K(C(8)H(5)N(2)O(6))](n), each ligand bridges six K(+) cations. The carboxyl­ate group coordinates both bidentately to one K(+) ion and monodentately to two K(+) ions, while one nitro group coordinates bidentately to a fourth K(+) ion. The last two K(+) ions are coordinated by the remaining nitro group, one in a bidentate fashion, the other monodentately through one O atom. This bridging mode results in a three-dimensional network. The coordination geometry of the K(+) ion is represented by an irregular KO(9) polyhedron. Very weak C—H⋯O inter­actions are observed in the crystal structure. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979411/ /pubmed/21579275 http://dx.doi.org/10.1107/S1600536810015400 Text en © Danish et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Danish, Muhammad
Saleem, Iram
Ahmad, Nazir
Starosta, Wojciech
Leciejewicz, Janusz
Poly[(μ(6)-2-methyl-3,5-dinitro­benzoato)potassium]
title Poly[(μ(6)-2-methyl-3,5-dinitro­benzoato)potassium]
title_full Poly[(μ(6)-2-methyl-3,5-dinitro­benzoato)potassium]
title_fullStr Poly[(μ(6)-2-methyl-3,5-dinitro­benzoato)potassium]
title_full_unstemmed Poly[(μ(6)-2-methyl-3,5-dinitro­benzoato)potassium]
title_short Poly[(μ(6)-2-methyl-3,5-dinitro­benzoato)potassium]
title_sort poly[(μ(6)-2-methyl-3,5-dinitro­benzoato)potassium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979411/
https://www.ncbi.nlm.nih.gov/pubmed/21579275
http://dx.doi.org/10.1107/S1600536810015400
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