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Poly[(μ(6)-2-methyl-3,5-dinitrobenzoato)potassium]
In the structure of the title coordination polymer, [K(C(8)H(5)N(2)O(6))](n), each ligand bridges six K(+) cations. The carboxylate group coordinates both bidentately to one K(+) ion and monodentately to two K(+) ions, while one nitro group coordinates bidentately to a fourth K(+) ion. The last two...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979411/ https://www.ncbi.nlm.nih.gov/pubmed/21579275 http://dx.doi.org/10.1107/S1600536810015400 |
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author | Danish, Muhammad Saleem, Iram Ahmad, Nazir Starosta, Wojciech Leciejewicz, Janusz |
author_facet | Danish, Muhammad Saleem, Iram Ahmad, Nazir Starosta, Wojciech Leciejewicz, Janusz |
author_sort | Danish, Muhammad |
collection | PubMed |
description | In the structure of the title coordination polymer, [K(C(8)H(5)N(2)O(6))](n), each ligand bridges six K(+) cations. The carboxylate group coordinates both bidentately to one K(+) ion and monodentately to two K(+) ions, while one nitro group coordinates bidentately to a fourth K(+) ion. The last two K(+) ions are coordinated by the remaining nitro group, one in a bidentate fashion, the other monodentately through one O atom. This bridging mode results in a three-dimensional network. The coordination geometry of the K(+) ion is represented by an irregular KO(9) polyhedron. Very weak C—H⋯O interactions are observed in the crystal structure. |
format | Text |
id | pubmed-2979411 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29794112010-12-30 Poly[(μ(6)-2-methyl-3,5-dinitrobenzoato)potassium] Danish, Muhammad Saleem, Iram Ahmad, Nazir Starosta, Wojciech Leciejewicz, Janusz Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title coordination polymer, [K(C(8)H(5)N(2)O(6))](n), each ligand bridges six K(+) cations. The carboxylate group coordinates both bidentately to one K(+) ion and monodentately to two K(+) ions, while one nitro group coordinates bidentately to a fourth K(+) ion. The last two K(+) ions are coordinated by the remaining nitro group, one in a bidentate fashion, the other monodentately through one O atom. This bridging mode results in a three-dimensional network. The coordination geometry of the K(+) ion is represented by an irregular KO(9) polyhedron. Very weak C—H⋯O interactions are observed in the crystal structure. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979411/ /pubmed/21579275 http://dx.doi.org/10.1107/S1600536810015400 Text en © Danish et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Danish, Muhammad Saleem, Iram Ahmad, Nazir Starosta, Wojciech Leciejewicz, Janusz Poly[(μ(6)-2-methyl-3,5-dinitrobenzoato)potassium] |
title | Poly[(μ(6)-2-methyl-3,5-dinitrobenzoato)potassium] |
title_full | Poly[(μ(6)-2-methyl-3,5-dinitrobenzoato)potassium] |
title_fullStr | Poly[(μ(6)-2-methyl-3,5-dinitrobenzoato)potassium] |
title_full_unstemmed | Poly[(μ(6)-2-methyl-3,5-dinitrobenzoato)potassium] |
title_short | Poly[(μ(6)-2-methyl-3,5-dinitrobenzoato)potassium] |
title_sort | poly[(μ(6)-2-methyl-3,5-dinitrobenzoato)potassium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979411/ https://www.ncbi.nlm.nih.gov/pubmed/21579275 http://dx.doi.org/10.1107/S1600536810015400 |
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