Bis(4-fluoro­anilinium) tetra­chloridocuprate(II)

The crystal structure of the title compound, (C(6)H(7)FN)(2)[CuCl(4)], consists of parallel two-dimensional perovskite-type layers of corner-sharing CuCl(6) octa­hedra. These are bonded together via N—H⋯Cl hydrogen bonds from the 4-fluoro­anilinium chains, which are almost perpendicular to the layer...

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Detalles Bibliográficos
Autores principales: Zhao, Min Min, Shi, Ping Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979418/
https://www.ncbi.nlm.nih.gov/pubmed/21579301
http://dx.doi.org/10.1107/S1600536810017289
Descripción
Sumario:The crystal structure of the title compound, (C(6)H(7)FN)(2)[CuCl(4)], consists of parallel two-dimensional perovskite-type layers of corner-sharing CuCl(6) octa­hedra. These are bonded together via N—H⋯Cl hydrogen bonds from the 4-fluoro­anilinium chains, which are almost perpendicular to the layers. The CuCl(4) dianions have two short Cu—Cl bonds [2.2657 (15) and 2.2884 (13) Å] and two longer bonds [2.8868 (15) Å], giving highly Jahn–Teller-distorted CuCl(6) octa­hedra. The Cu atoms are situated on crystallographic centers of inversion.

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