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Bis(4-fluoroanilinium) tetrachloridocuprate(II)
The crystal structure of the title compound, (C(6)H(7)FN)(2)[CuCl(4)], consists of parallel two-dimensional perovskite-type layers of corner-sharing CuCl(6) octahedra. These are bonded together via N—H⋯Cl hydrogen bonds from the 4-fluoroanilinium chains, which are almost perpendicular to the layer...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979418/ https://www.ncbi.nlm.nih.gov/pubmed/21579301 http://dx.doi.org/10.1107/S1600536810017289 |
| _version_ | 1782191407893577728 |
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| author | Zhao, Min Min Shi, Ping Ping |
| author_facet | Zhao, Min Min Shi, Ping Ping |
| author_sort | Zhao, Min Min |
| collection | PubMed |
| description | The crystal structure of the title compound, (C(6)H(7)FN)(2)[CuCl(4)], consists of parallel two-dimensional perovskite-type layers of corner-sharing CuCl(6) octahedra. These are bonded together via N—H⋯Cl hydrogen bonds from the 4-fluoroanilinium chains, which are almost perpendicular to the layers. The CuCl(4) dianions have two short Cu—Cl bonds [2.2657 (15) and 2.2884 (13) Å] and two longer bonds [2.8868 (15) Å], giving highly Jahn–Teller-distorted CuCl(6) octahedra. The Cu atoms are situated on crystallographic centers of inversion. |
| format | Text |
| id | pubmed-2979418 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29794182010-12-30 Bis(4-fluoroanilinium) tetrachloridocuprate(II) Zhao, Min Min Shi, Ping Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, (C(6)H(7)FN)(2)[CuCl(4)], consists of parallel two-dimensional perovskite-type layers of corner-sharing CuCl(6) octahedra. These are bonded together via N—H⋯Cl hydrogen bonds from the 4-fluoroanilinium chains, which are almost perpendicular to the layers. The CuCl(4) dianions have two short Cu—Cl bonds [2.2657 (15) and 2.2884 (13) Å] and two longer bonds [2.8868 (15) Å], giving highly Jahn–Teller-distorted CuCl(6) octahedra. The Cu atoms are situated on crystallographic centers of inversion. International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979418/ /pubmed/21579301 http://dx.doi.org/10.1107/S1600536810017289 Text en © Zhao and Shi 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhao, Min Min Shi, Ping Ping Bis(4-fluoroanilinium) tetrachloridocuprate(II) |
| title | Bis(4-fluoroanilinium) tetrachloridocuprate(II) |
| title_full | Bis(4-fluoroanilinium) tetrachloridocuprate(II) |
| title_fullStr | Bis(4-fluoroanilinium) tetrachloridocuprate(II) |
| title_full_unstemmed | Bis(4-fluoroanilinium) tetrachloridocuprate(II) |
| title_short | Bis(4-fluoroanilinium) tetrachloridocuprate(II) |
| title_sort | bis(4-fluoroanilinium) tetrachloridocuprate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979418/ https://www.ncbi.nlm.nih.gov/pubmed/21579301 http://dx.doi.org/10.1107/S1600536810017289 |
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